Given the following proposed mechanism, predict the rate law for the overall reaction. 2NO2 + Cl2 → 2NO2C1 (overall reaction) Mechanism NO2 + Cl2 → NO2C1 + Cl slow NO2 + Cl → NO2CI fast Rate = k[NO2J°[Cl»]? Rate = k[NO2][Cl2] %3D Rate = k[NO2C1]²[CI] Rate = k[NO2][Cl]? Rate = k[NO2C1][CI] %3D

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Given the following proposed mechanism, predict the rate law for the overall reaction.
2NO2 + Cl2 –→ 2NO2C1 (overall reaction)
Mechanism
NO2 + Cl2 → NO2 Cl + Cl slow
NO2 + Cl → NO2CI fast
Rate = k[NO2]²[Cl»]?
Rate = k[NO2][C2]
%3D
Rate = k[NO2 Cl]² [Ci]
O Rate = k[NO2][Ci]²
Rate = k[NO2 Cl][Ci]
Transcribed Image Text:Given the following proposed mechanism, predict the rate law for the overall reaction. 2NO2 + Cl2 –→ 2NO2C1 (overall reaction) Mechanism NO2 + Cl2 → NO2 Cl + Cl slow NO2 + Cl → NO2CI fast Rate = k[NO2]²[Cl»]? Rate = k[NO2][C2] %3D Rate = k[NO2 Cl]² [Ci] O Rate = k[NO2][Ci]² Rate = k[NO2 Cl][Ci]
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