Give the systematic name for each complex ion and select the oxidation number of each metal species. [FeCl (ox)]³: Incorrect Fe oxidation number: [Cu(OH)(OH₂),1² +: pentaaquahydroxocopper(III) Incorrect Cu oxidation number: +3
Give the systematic name for each complex ion and select the oxidation number of each metal species. [FeCl (ox)]³: Incorrect Fe oxidation number: [Cu(OH)(OH₂),1² +: pentaaquahydroxocopper(III) Incorrect Cu oxidation number: +3
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Oxidation State and Systematic Naming of Complex Ions
#### Example Assignment:
**Objective:**
- Provide the systematic name for each complex ion.
- Determine and select the correct oxidation number of each metal species in the given complex ions.
---
**Complex Ion: [FeCl4(ox)]3−**
- **Oxidation State of Fe:**
- Your initial attempt: **+3**
- Feedback: Incorrect
**Complex Ion: [Cu(OH)(OH2)5]2+**
- **Systematic Name:**
- Your initial attempt: **pentaaquahydroxo copper (III)**
- Feedback: Incorrect
- Correction:
- Note: The ligand **OH−** should be named as **hydroxido**, not **hydroxo**.
- Also, remember to add **"ion"** at the end of the complex cation name.
- **Oxidation State of Cu:**
- Your initial attempt: **+3**
- Feedback: Incorrect
---
### Corrected Information:
**Tips for Naming and Determining Oxidation States:**
1. **Naming Ligands:**
- **Aqua** for H₂O
- **Hydroxido** for OH− (not hydroxo)
2. **Oxidation States:**
- Verify the sum of the oxidation states within the complex matches the overall charge of the ion.
**Example Correction:**
- The correct systematic naming should follow IUPAC conventions strictly using appropriate ligand names and noting the charge correctly.
- For the [Cu(OH)(OH2)5]2+ complex, the corrected name should be **pentaaquahydroxidocopper(II) ion** to reflect the proper oxidation state and ligand name.
### Educational Notes:
- **IUPAC Naming Conventions:** Ensure the proper IUPAC name is used for each ligand in the coordination complex.
- **Oxidation State Calculation:** Check to ensure the sum of the oxidation states of the metal and its ligands equals the ion's overall charge.
By adhering to these rules, students can accurately name coordination complexes and determine the correct oxidation states of the metal centers.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1b99c910-aabd-4bff-9c76-8ab2f9147b49%2F9afeedfb-615c-472a-9d29-affc66615b42%2Ftlxiey_processed.png&w=3840&q=75)
Transcribed Image Text:### Oxidation State and Systematic Naming of Complex Ions
#### Example Assignment:
**Objective:**
- Provide the systematic name for each complex ion.
- Determine and select the correct oxidation number of each metal species in the given complex ions.
---
**Complex Ion: [FeCl4(ox)]3−**
- **Oxidation State of Fe:**
- Your initial attempt: **+3**
- Feedback: Incorrect
**Complex Ion: [Cu(OH)(OH2)5]2+**
- **Systematic Name:**
- Your initial attempt: **pentaaquahydroxo copper (III)**
- Feedback: Incorrect
- Correction:
- Note: The ligand **OH−** should be named as **hydroxido**, not **hydroxo**.
- Also, remember to add **"ion"** at the end of the complex cation name.
- **Oxidation State of Cu:**
- Your initial attempt: **+3**
- Feedback: Incorrect
---
### Corrected Information:
**Tips for Naming and Determining Oxidation States:**
1. **Naming Ligands:**
- **Aqua** for H₂O
- **Hydroxido** for OH− (not hydroxo)
2. **Oxidation States:**
- Verify the sum of the oxidation states within the complex matches the overall charge of the ion.
**Example Correction:**
- The correct systematic naming should follow IUPAC conventions strictly using appropriate ligand names and noting the charge correctly.
- For the [Cu(OH)(OH2)5]2+ complex, the corrected name should be **pentaaquahydroxidocopper(II) ion** to reflect the proper oxidation state and ligand name.
### Educational Notes:
- **IUPAC Naming Conventions:** Ensure the proper IUPAC name is used for each ligand in the coordination complex.
- **Oxidation State Calculation:** Check to ensure the sum of the oxidation states of the metal and its ligands equals the ion's overall charge.
By adhering to these rules, students can accurately name coordination complexes and determine the correct oxidation states of the metal centers.
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