Give the spectroscopic analysis and the structure of the product using the following

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

Give the spectroscopic analysis and the structure of the product using the following










H NMR CHARACTERISTIC CHEMICAL SHIFTS / ppm
Characteristic IR Stretching Frequencies
R= methyl
methylene
methyne
-CH
other
-CH,
-CH
The Five Zones
0.9
1.4
1,5
sp'C-OH
1-5
Stretching Frequency
Zone 1:4000 - 3200 cm-1
Bond
Intensity and Shape
spC-NH
1-3
1.6
2.3
2.6
25
Alcohol O-H
3650- 3200
CECH
3500 - 3200
3340 - 3250
usually strong and broad
r medium, broad
strong and sharp
Amine or Amide N-H
Alkyne aC-H
2.1
2.4
2.5
4.5-6.5
Zone 2: 3200 - 2700 cm-1
R-N
H
65-8
2.2
2.5
2.9
Aryl or vinyl sp C-H
Alkyl sp' C-H
Aldehyde C-H
Carboxylic acid O-H
3100 - 3000
2900- 2850
variable
vàriable
2.3
2.7
3.0
medium, 2 peaks
strong, very broad
9-10
2850, 2750
R
3100- 2500
R-Br
2.7
3.3
4.1
Zone 3: 2400-2100 cm
9-12
R-CI
3.1
3.4
4.1
variable and sharp
variable and sharp
Alkyne CC
2260 - 2000
R
OH
Nitrile CHN
2300 - 2220
R-0-
3.3
3.4
3.7
Zone 4: 1850-1650 cm
1740- 1705
Ketone C-0
strong
1740-1710
1750- 1735
strong
strong
Aldehyde CO
13C NMR CHARACTERISTIC CHEMICAL SHIFTS / ppm
Ester C-O
Carboxylic acid C-O
1725-1700
1690- 1650
strong
strong
cmet e-a.C-
c-a.c-
Amide CO
Zone 5: 1650- 1500 cm
-c-0-
alkan
varlable
1680 - 1620
1650 - 1600
Alkene C-C
Benzene ring CC
variable
L L LLL
130
a-unsat. shifuad ca. 30 cm to lower wavenumber
- TMS
TMS
CS Scanned with CamScanner
AICI,
anisole
QE-300
240
220
200
180
160
140
100
12
11
10
Transcribed Image Text:H NMR CHARACTERISTIC CHEMICAL SHIFTS / ppm Characteristic IR Stretching Frequencies R= methyl methylene methyne -CH other -CH, -CH The Five Zones 0.9 1.4 1,5 sp'C-OH 1-5 Stretching Frequency Zone 1:4000 - 3200 cm-1 Bond Intensity and Shape spC-NH 1-3 1.6 2.3 2.6 25 Alcohol O-H 3650- 3200 CECH 3500 - 3200 3340 - 3250 usually strong and broad r medium, broad strong and sharp Amine or Amide N-H Alkyne aC-H 2.1 2.4 2.5 4.5-6.5 Zone 2: 3200 - 2700 cm-1 R-N H 65-8 2.2 2.5 2.9 Aryl or vinyl sp C-H Alkyl sp' C-H Aldehyde C-H Carboxylic acid O-H 3100 - 3000 2900- 2850 variable vàriable 2.3 2.7 3.0 medium, 2 peaks strong, very broad 9-10 2850, 2750 R 3100- 2500 R-Br 2.7 3.3 4.1 Zone 3: 2400-2100 cm 9-12 R-CI 3.1 3.4 4.1 variable and sharp variable and sharp Alkyne CC 2260 - 2000 R OH Nitrile CHN 2300 - 2220 R-0- 3.3 3.4 3.7 Zone 4: 1850-1650 cm 1740- 1705 Ketone C-0 strong 1740-1710 1750- 1735 strong strong Aldehyde CO 13C NMR CHARACTERISTIC CHEMICAL SHIFTS / ppm Ester C-O Carboxylic acid C-O 1725-1700 1690- 1650 strong strong cmet e-a.C- c-a.c- Amide CO Zone 5: 1650- 1500 cm -c-0- alkan varlable 1680 - 1620 1650 - 1600 Alkene C-C Benzene ring CC variable L L LLL 130 a-unsat. shifuad ca. 30 cm to lower wavenumber - TMS TMS CS Scanned with CamScanner AICI, anisole QE-300 240 220 200 180 160 140 100 12 11 10
a. IR
Frequency (cm-1)
Bond Assignment
b. NMR
Chemical Shift(J)
Multiplicity
Assignment
Structure of Product
CS Scanned with CamScanner
Transcribed Image Text:a. IR Frequency (cm-1) Bond Assignment b. NMR Chemical Shift(J) Multiplicity Assignment Structure of Product CS Scanned with CamScanner
Expert Solution
steps

Step by step

Solved in 2 steps with 6 images

Blurred answer
Knowledge Booster
Mass Spectrometry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY