Give the complete mechanism, including transition states, for the following reaction. Then draw the potential energy diagram for it and for similar alkylbromides of other substitution patterns. Give the rate law for this type of mechanism. Then give the rate trend based on substitution pattern and explain it using the rate law and potential energy diagram you have provided. Use additional sheets, make sure you draw large enough for your work to be clearly understood, and attach them in order. H" -CI HSCH3 ethanol H3CS- + H" -SCH 3 Explain why 1-chlorobicyclo[2.2.1]heptane (shown below) even though it is a tertiary alkyl halide, is virtually unreactive in the SN1 reaction. It has been estimated that it is 10-13 times as reactive as tert-butyl chloride. Hint: consider the preferred geometry of the reactive intermediate.

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Give the complete mechanism, including transition states, for the following reaction.
Then draw the potential energy diagram for it and for similar alkylbromides of other
substitution patterns. Give the rate law for this type of mechanism. Then give the rate trend
based on substitution pattern and explain it using the rate law and potential energy diagram
you have provided. Use additional sheets, make sure you draw large enough for your work to be
clearly understood, and attach them in order.
H"
-CI
HSCH3
ethanol
H3CS-
+
H"
-SCH 3
Explain why 1-chlorobicyclo[2.2.1]heptane (shown below) even though it is a tertiary
alkyl halide, is virtually unreactive in the SN1 reaction. It has been estimated that it is 10-13
times as reactive as tert-butyl chloride. Hint: consider the preferred geometry of the reactive
intermediate.
Transcribed Image Text:Give the complete mechanism, including transition states, for the following reaction. Then draw the potential energy diagram for it and for similar alkylbromides of other substitution patterns. Give the rate law for this type of mechanism. Then give the rate trend based on substitution pattern and explain it using the rate law and potential energy diagram you have provided. Use additional sheets, make sure you draw large enough for your work to be clearly understood, and attach them in order. H" -CI HSCH3 ethanol H3CS- + H" -SCH 3 Explain why 1-chlorobicyclo[2.2.1]heptane (shown below) even though it is a tertiary alkyl halide, is virtually unreactive in the SN1 reaction. It has been estimated that it is 10-13 times as reactive as tert-butyl chloride. Hint: consider the preferred geometry of the reactive intermediate.
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