Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![**Formation of iodine from iodide.**
- Assign oxidation numbers to each atom.
- Identify the oxidizing agent and the reducing agent.
**Reaction:**
\[ 2 \text{I}^- (aq) + \text{MnO}_2(s) + 4 \text{H}^+ (aq) \rightarrow \text{I}_2(s) + \text{Mn}^{2+}(aq) + 2 \text{H}_2\text{O}(l) \]
**Explanation:**
1. **Oxidation Numbers**:
- Iodide (\(\text{I}^-\)) has an oxidation number of -1.
- Iodine (\(\text{I}_2\)) has an oxidation number of 0.
- Manganese in \(\text{MnO}_2\) has an oxidation number of +4.
- Manganese in \(\text{Mn}^{2+}\) has an oxidation number of +2.
- Hydrogen (\(\text{H}^+\)) has an oxidation number of +1.
- Oxygen in water (\(\text{H}_2\text{O}\)) and in \(\text{MnO}_2\) has an oxidation number of -2.
2. **Identifying the Agents**:
- **Oxidizing Agent**: MnO\(_2\) (Manganese is reduced from +4 to +2)
- **Reducing Agent**: I\(^-\) (Iodide is oxidized from -1 to 0)
This reaction illustrates the process of a redox reaction, where iodide ions are oxidized to iodine, and manganese dioxide is reduced to Mn\(^{2+}\) ions.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F081cd3d5-be26-4896-83a7-8d497d45a428%2Fd78ed4a5-ccfa-401e-8899-6b8d3825c871%2Fa193h217_processed.png&w=3840&q=75)
Transcribed Image Text:**Formation of iodine from iodide.**
- Assign oxidation numbers to each atom.
- Identify the oxidizing agent and the reducing agent.
**Reaction:**
\[ 2 \text{I}^- (aq) + \text{MnO}_2(s) + 4 \text{H}^+ (aq) \rightarrow \text{I}_2(s) + \text{Mn}^{2+}(aq) + 2 \text{H}_2\text{O}(l) \]
**Explanation:**
1. **Oxidation Numbers**:
- Iodide (\(\text{I}^-\)) has an oxidation number of -1.
- Iodine (\(\text{I}_2\)) has an oxidation number of 0.
- Manganese in \(\text{MnO}_2\) has an oxidation number of +4.
- Manganese in \(\text{Mn}^{2+}\) has an oxidation number of +2.
- Hydrogen (\(\text{H}^+\)) has an oxidation number of +1.
- Oxygen in water (\(\text{H}_2\text{O}\)) and in \(\text{MnO}_2\) has an oxidation number of -2.
2. **Identifying the Agents**:
- **Oxidizing Agent**: MnO\(_2\) (Manganese is reduced from +4 to +2)
- **Reducing Agent**: I\(^-\) (Iodide is oxidized from -1 to 0)
This reaction illustrates the process of a redox reaction, where iodide ions are oxidized to iodine, and manganese dioxide is reduced to Mn\(^{2+}\) ions.
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