Formation of iodine from iodide. Assign oxidation numbers to each atom. Identify the oxidizing agent and the reducing agent.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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**Formation of iodine from iodide.**

- Assign oxidation numbers to each atom.
- Identify the oxidizing agent and the reducing agent.

**Reaction:**

\[ 2 \text{I}^- (aq) + \text{MnO}_2(s) + 4 \text{H}^+ (aq) \rightarrow \text{I}_2(s) + \text{Mn}^{2+}(aq) + 2 \text{H}_2\text{O}(l) \]

**Explanation:**

1. **Oxidation Numbers**:
   - Iodide (\(\text{I}^-\)) has an oxidation number of -1.
   - Iodine (\(\text{I}_2\)) has an oxidation number of 0.
   - Manganese in \(\text{MnO}_2\) has an oxidation number of +4.
   - Manganese in \(\text{Mn}^{2+}\) has an oxidation number of +2.
   - Hydrogen (\(\text{H}^+\)) has an oxidation number of +1.
   - Oxygen in water (\(\text{H}_2\text{O}\)) and in \(\text{MnO}_2\) has an oxidation number of -2.

2. **Identifying the Agents**:
   - **Oxidizing Agent**: MnO\(_2\) (Manganese is reduced from +4 to +2)
   - **Reducing Agent**: I\(^-\) (Iodide is oxidized from -1 to 0)

This reaction illustrates the process of a redox reaction, where iodide ions are oxidized to iodine, and manganese dioxide is reduced to Mn\(^{2+}\) ions.
Transcribed Image Text:**Formation of iodine from iodide.** - Assign oxidation numbers to each atom. - Identify the oxidizing agent and the reducing agent. **Reaction:** \[ 2 \text{I}^- (aq) + \text{MnO}_2(s) + 4 \text{H}^+ (aq) \rightarrow \text{I}_2(s) + \text{Mn}^{2+}(aq) + 2 \text{H}_2\text{O}(l) \] **Explanation:** 1. **Oxidation Numbers**: - Iodide (\(\text{I}^-\)) has an oxidation number of -1. - Iodine (\(\text{I}_2\)) has an oxidation number of 0. - Manganese in \(\text{MnO}_2\) has an oxidation number of +4. - Manganese in \(\text{Mn}^{2+}\) has an oxidation number of +2. - Hydrogen (\(\text{H}^+\)) has an oxidation number of +1. - Oxygen in water (\(\text{H}_2\text{O}\)) and in \(\text{MnO}_2\) has an oxidation number of -2. 2. **Identifying the Agents**: - **Oxidizing Agent**: MnO\(_2\) (Manganese is reduced from +4 to +2) - **Reducing Agent**: I\(^-\) (Iodide is oxidized from -1 to 0) This reaction illustrates the process of a redox reaction, where iodide ions are oxidized to iodine, and manganese dioxide is reduced to Mn\(^{2+}\) ions.
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