For the reaction 2NO + Cl2 --> 2NOCl Match the appropriate rate law to each postulated mechanism. A Rate = k[NO]2[Cl2]2 B Rate = k[NO][Cl2]2 C Rate = k[Cl2] D Rate = k[Cl2]2 E Rate = k[NO] F Rate = k[NO][Cl2] G Rate = k[NO]2[Cl2] H Rate = k[NO]2 I None of the above C Cl2 = 2Cl slow Cl + NO = NOCl fast G 2NO = N2O2 fast equilibrium N2O2 + Cl2 = 2NOCl slow I NO + Cl2 = NOCl2 fast equilibrium 2NOCl2 = NOCl3 + NOCl slow NOCl3 = NOCl + Cl2 fast F NO + Cl2 = NOCl + Cl slow Cl + NO = NOCl fast
For the reaction 2NO + Cl2 --> 2NOCl Match the appropriate rate law to each postulated mechanism. A Rate = k[NO]2[Cl2]2 B Rate = k[NO][Cl2]2 C Rate = k[Cl2] D Rate = k[Cl2]2 E Rate = k[NO] F Rate = k[NO][Cl2] G Rate = k[NO]2[Cl2] H Rate = k[NO]2 I None of the above C Cl2 = 2Cl slow Cl + NO = NOCl fast G 2NO = N2O2 fast equilibrium N2O2 + Cl2 = 2NOCl slow I NO + Cl2 = NOCl2 fast equilibrium 2NOCl2 = NOCl3 + NOCl slow NOCl3 = NOCl + Cl2 fast F NO + Cl2 = NOCl + Cl slow Cl + NO = NOCl fast
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 4E: A study of the rate of dimerization of C4H6 gave the data shown in the table: 2C4H6C8H12 (a)...
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Question
For the reaction
2NO + Cl2 --> 2NOCl
Match the appropriate rate law to each postulated mechanism.
A Rate = k[NO]2[Cl2]2
B Rate = k[NO][Cl2]2
C Rate = k[Cl2]
D Rate = k[Cl2]2
E Rate = k[NO]
F Rate = k[NO][Cl2]
G Rate = k[NO]2[Cl2]
H Rate = k[NO]2
I None of the above
C
Cl2 = 2Cl slow
Cl + NO = NOCl fast
G
2NO = N2O2 fast equilibrium
N2O2 + Cl2 = 2NOCl slow
I
NO + Cl2 = NOCl2 fast equilibrium
2NOCl2 = NOCl3 + NOCl slow
NOCl3 = NOCl + Cl2 fast
F
NO + Cl2 = NOCl + Cl slow
Cl + NO = NOCl fast
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