For the gas phase decomposition of t-butyl acetate, CH3COOC(CH3)3–(CH3)½C=CH, + CH;COOH the rate constant in s' has been determined at several temperatures. When In k is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -2.04×104 K and a y-intercept of 30.7. The value of the rate constant for the gas phase decomposition of t-butyl acetate at 511 K is (Enter your answer to one significant figure.)

For the gas phase decomposition of t-butyl acetate, CH3COOC(CH3)3–(CH3)½C=CH, + CH;COOH the rate constant in s' has been determined at several temperatures. When In k is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -2.04×104 K and a y-intercept of 30.7. The value of the rate constant for the gas phase decomposition of t-butyl acetate at 511 K is (Enter your answer to one significant figure.)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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In a study of the rearrangement of cyclopropane to propene at 500 °C (CH2)3 CH3CH=CH2 the concentration of (CH2)3 was followed as a function of time. It was found that a graph of In[(CH2)3] versus time in seconds gave a straight line with a slope of -9.38×104 s1 and a y-intercept of -1.57 . Based on this plot, the reaction is O order in (CH2)3 and the half life for the first reaction is seconds.
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For the gas phase decomposition of t-butyl bromide,(CH3)3CBr(CH3)2C=CH2 + HBrthe rate constant in s-1 has been determined at several temperatures. When ln k is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -2.04×104 K and a y-intercept of 30.6. The value of the rate constant for the gas phase decomposition of t-butyl bromide at 543 K is _________ s-1. (Enter your answer to one significant figure.)
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