For the gas phase decomposition of t-butyl chloride, (CH3)3CC→(CH3)2C=CH2 + HCI the rate constant in s- has been determined at several temperatures. When In k is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -2.08×104 K and a y-intercept of 28.6. The value of the rate constant for the gas phase decomposition of t-butyl chloride at 582 K is (Enter your answer to one significant figure.)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
For the gas phase decomposition of t-butyl chloride,

\[
\text{(CH}_3\text{)}_3\text{CCl} \longrightarrow \text{(CH}_3\text{)}_2\text{C=CH}_2 + \text{HCl}
\]

the rate constant in s\(^{-1}\) has been determined at several temperatures. When \(\ln k\) is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of \(-2.08 \times 10^4\) K and a y-intercept of 28.6.

The value of the rate constant for the gas phase decomposition of t-butyl chloride at 582 K is \(\_\_\_\_\_\) s\(^{-1}\).

(Enter your answer to one significant figure.)
Transcribed Image Text:For the gas phase decomposition of t-butyl chloride, \[ \text{(CH}_3\text{)}_3\text{CCl} \longrightarrow \text{(CH}_3\text{)}_2\text{C=CH}_2 + \text{HCl} \] the rate constant in s\(^{-1}\) has been determined at several temperatures. When \(\ln k\) is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of \(-2.08 \times 10^4\) K and a y-intercept of 28.6. The value of the rate constant for the gas phase decomposition of t-butyl chloride at 582 K is \(\_\_\_\_\_\) s\(^{-1}\). (Enter your answer to one significant figure.)
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY