For the following structure, draw and indicate the low and high-energy chair conformations AND calculate the energy difference between the two conformations using the table provided. Me ECLIPSING Interactions AB H/H H/Me H/Et Energy kcal/mol 1.0 1.4 1.5 H/H-Pr 1.6 H/t-Bu 3.0 Me / Me 2.6 Me / Et 2.7 Me //-Pr 3.0 GAUCHE A. Interactions Me / Me Me / Et Me //-Pr Me/t-Bu Et / Et Et/i-Pr Et/t-Bu i-Pr/i-Pr Energy kcal/mol 0.9 0.95 1.1 2.7 1.1 1.6 3.0 2.0

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For the following structure, draw and indicate the low and high-energy chair
conformations AND calculate the energy difference between the two conformations
using the table provided.
ECLIPSING
Interactions
AB
Energy
kcal/mol
https://www.pharm...
H/H 1.0
1.4
H/Me
H/Et 1.5
H/H-Pr 1.6
H/t-Bu 3.0
Me / Me 2.6
Me / Et 2.7
Me //-Pr 3.0
GAUCHE A.
Interactions
Energy
kcal/mol
Me / Me
Me / Et
Me //-Pr
1.1
Me/t-Bu
2.7
1.1
Et / Et
Et/i-Pr
1.6
Et/(-Bu 3.0
i-Pr/i-Pr 2.0
0.9
0.95
Click here to preview image
Part A) Assign BOTH IR spectra below to TWO of the FOUR
provided structures A - D. TWO of the four structures do NOT
match to the provided spectra at all.
Part B) Identify the peaks that are associated with specific bonds
of the structure and list the corresponding functional group that
the specific bonds belong to. Re-create the example table below
that organizes this information. Use the wavenumbers that are
already labeled on the spectra.
Example table (EACH spectrum needs to have a table):
Wee
Transcribed Image Text:e nts SUO a Amazon.com f Facebook utoring Policies D 四 Me YouTube To preview the image Click Here For the following structure, draw and indicate the low and high-energy chair conformations AND calculate the energy difference between the two conformations using the table provided. ECLIPSING Interactions AB Energy kcal/mol https://www.pharm... H/H 1.0 1.4 H/Me H/Et 1.5 H/H-Pr 1.6 H/t-Bu 3.0 Me / Me 2.6 Me / Et 2.7 Me //-Pr 3.0 GAUCHE A. Interactions Energy kcal/mol Me / Me Me / Et Me //-Pr 1.1 Me/t-Bu 2.7 1.1 Et / Et Et/i-Pr 1.6 Et/(-Bu 3.0 i-Pr/i-Pr 2.0 0.9 0.95 Click here to preview image Part A) Assign BOTH IR spectra below to TWO of the FOUR provided structures A - D. TWO of the four structures do NOT match to the provided spectra at all. Part B) Identify the peaks that are associated with specific bonds of the structure and list the corresponding functional group that the specific bonds belong to. Re-create the example table below that organizes this information. Use the wavenumbers that are already labeled on the spectra. Example table (EACH spectrum needs to have a table): Wee
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