Determine for each of the following pairs of molecules whether they are identical, constitutional isomers, or stereoisomers. OH II and OH and -OH OH OH OH and OH www CI and CI OH
Determine for each of the following pairs of molecules whether they are identical, constitutional isomers, or stereoisomers. OH II and OH and -OH OH OH OH and OH www CI and CI OH
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Title:** Understanding Molecular Isomerism
**Objective:**
Examine each pair of molecules and determine if they are identical, constitutional isomers, or stereoisomers.
**Molecule Pairs:**
1. **Pair 1:**
- Structure: Two cyclic hexane rings with hydroxyl (OH) groups attached.
- Both structures are shown as chair conformations with differing orientations of the OH groups.
2. **Pair 2:**
- Structure: Two cyclohexane molecules with two hydroxyl (OH) groups.
- The positions of the OH groups differ on the cyclohexane ring.
3. **Pair 3:**
- Structure: Two linear chains with identical carbon skeletons, differing only in the placement of substituents.
- Both structures depict a similar shape with variances in branching.
4. **Pair 4:**
- Structure: Two similar linear carbon chains with chlorine (Cl) atoms.
- The Cl atoms are depicted in different stereochemical orientations (dashed and solid wedges indicate stereochemistry).
**Instructions:**
- Evaluate each pair carefully.
- Consider the connectivity of atoms for constitutional isomers.
- Assess stereochemistry and spatial arrangement for stereoisomers.
- Utilize molecular models if necessary for visualization.
This exercise aids in recognizing different types of isomerism in organic chemistry.
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