For the following cyanine dye molecule, particle-in-a-box (PIB) theory works well, H₂C CH3 Based on the PIB modeling, which of the following statements is (are) correct? 1. The box length is taken as the distance between the two nitrogen atoms. II. The length of chain between the atoms nitrogen could not be estimated using number of carbon atoms in the conugated system. III. The carbon atoms in the fused rings disrupt the conjugated linear system of PIB OA. All the three statements are correct B. Both I and III are correct C. Both II and III are correct O D.Only I is correct O E. Only III is correct

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For the following cyanine dye molecule,
particle-in-a-box (PIB) theory works well,
H₂C
CH3
Based on the PIB modeling, which of the
following statements is (are) correct?
1. The box length is taken as the distance
between the two nitrogen atoms.
II. The length of chain between the atoms
nitrogen could not be estimated using
number of carbon atoms in the conugated
system.
III. The carbon atoms in the fused rings
disrupt the conjugated linear system of PIB
OA. All the three statements are correct
B. Both I and III are correct
C. Both II and III are correct
O D.Only I is correct
O E. Only III is correct
Transcribed Image Text:For the following cyanine dye molecule, particle-in-a-box (PIB) theory works well, H₂C CH3 Based on the PIB modeling, which of the following statements is (are) correct? 1. The box length is taken as the distance between the two nitrogen atoms. II. The length of chain between the atoms nitrogen could not be estimated using number of carbon atoms in the conugated system. III. The carbon atoms in the fused rings disrupt the conjugated linear system of PIB OA. All the three statements are correct B. Both I and III are correct C. Both II and III are correct O D.Only I is correct O E. Only III is correct
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