For most ketones, hydrate formation is unfavorable, because the equilibrium favors the ketone rather than the hydrate. However, the equilibrium for hydration of hexafluoroacetone favors formation of the hydrate. Provide a plausible explanation for this observation. + H₂O 1 F3C CF3 HO OH F3C CF3 > 99.99% CF3 group donate electron density. So, they decrease the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. ⚫ CF3 groups withdraw electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. CF 3 groups withdraw electron density. So, they decrease the electrophilicity of the carbonyl group resulting in a decrease in the energy of the reactants. In this case, the equilibrium favors the hydrate. O CF3 group donate electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate.

For most ketones, hydrate formation is unfavorable, because the equilibrium favors the ketone rather than the hydrate. However, the equilibrium for hydration of hexafluoroacetone favors formation of the hydrate. Provide a plausible explanation for this observation. + H₂O 1 F3C CF3 HO OH F3C CF3 > 99.99% CF3 group donate electron density. So, they decrease the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. ⚫ CF3 groups withdraw electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. CF 3 groups withdraw electron density. So, they decrease the electrophilicity of the carbonyl group resulting in a decrease in the energy of the reactants. In this case, the equilibrium favors the hydrate. O CF3 group donate electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

is this correct? Paracetamol consists of an aromatic ring to which a hydroxy group (-OH) is attached, forming a phenol. Attached to the aromatic ring is also an acetamide group, which consists of an acetyl group bound to a nitrogen atom.
Rank the following acids in decreasing acidity. Explain your answer CH2ClCOOH, CHCl2COOH, CH3COOH
Do not give handwriting solution.
Give detailed solution of the question and i request you please give the explanation of correct and incorrect option
compare and construct the nucleophilic reactions of hcl with propanone, propanal and propan-1-0
Carbonic anhydrase, an enzyme that converts carbon dioxide and water to carbonic acid as shown below, functions in the blood at an optimum pH of 7.0-7.5. Which of the following will lower the rate of carbonic anhydrase- catalyzed reaction? CO2 + H2O Carbonic anhydrase H₂CO3 O increasing the concentration of carbon dioxide O running the reaction at 4 °C carrying out the reaction at pH 7.2 O adding more carbonic anhydrase
Show how acid derivatives hydrolyze to carboxylic acids under either acidic or basicconditions. Explain why some acid derivatives (amides, for example) require muchstronger conditions for hydrolysis than other derivatives.
Explain the differences in pKa (vs. benzoic acid) of these substituted benzoic acids based on fundamental chemical principles (not just what pKa means).
need help with chemistry reactions questions
Explain Characteristic Spectroscopic Absorptions of Carboxylic Acid Derivatives ?
This CAN NOT be hand-drawn. Please type out all explanations. Please utilize a computer program to illustrate any examples! Thank you.
Indicate which is more acidic: 4-nitrophenol or 4-chlorophenol. Explain the reason.