For most ketones, hydrate formation is unfavorable, because the equilibrium favors the ketone rather than the hydrate. However, the equilibrium for hydration of hexafluoroacetone favors formation of the hydrate. Provide a plausible explanation for this observation. + H₂O 1 F3C CF3 HO OH F3C CF3 > 99.99% CF3 group donate electron density. So, they decrease the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. ⚫ CF3 groups withdraw electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. CF 3 groups withdraw electron density. So, they decrease the electrophilicity of the carbonyl group resulting in a decrease in the energy of the reactants. In this case, the equilibrium favors the hydrate. O CF3 group donate electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate.

For most ketones, hydrate formation is unfavorable, because the equilibrium favors the ketone rather than the hydrate. However, the equilibrium for hydration of hexafluoroacetone favors formation of the hydrate. Provide a plausible explanation for this observation. + H₂O 1 F3C CF3 HO OH F3C CF3 > 99.99% CF3 group donate electron density. So, they decrease the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. ⚫ CF3 groups withdraw electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate. CF 3 groups withdraw electron density. So, they decrease the electrophilicity of the carbonyl group resulting in a decrease in the energy of the reactants. In this case, the equilibrium favors the hydrate. O CF3 group donate electron density. So, they increase the electrophilicity of the carbonyl group resulting in an increase in the energy of the reactants. In this case, the equilibrium favors the hydrate.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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