For each system listed in the first column of the table below, decide (if possible) whether the change described in the second column will increase the entropy S of the system, decrease S, or leave S unchanged. If you don't have enough information to decide, check the "not enough information" butto the last column. System Change AS AS < 0 AS = 0 The carbon dioxide is cooled from 51.0 °C to -13.0 °C while the volume is held constant at 7.0 L. A few moles of carbon dioxide (CO,) gas. O AS > 0 not enough information O AS < 0 O AS = 0 The ammonia condenses to a liquid at a constant temperature of -14.0 °C. A few grams of ammonia vapor (NH3). O AS > 0 not enough information O As < 0 The helium is cooled from 72.0 °C to O AS = 0 -6.0 °C and is also compressed from a volume of 7.0 L to a volume of A few moles of helium (He) gas. O AS > 0 2.0 L. not enough information O O O O
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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