A 0.497 g sample of liquid C5H12 was combusted using excess oxygen gas inside a bomb calorimeter, with the products being carbon dioxide gas and liquid water. The calorimeter's heat capacity is 5.914 kJ °C-1. If the temperature inside the calorimeter increased from 25.0 °C to 29.6 °C, determine A₁U for this reaction in kJ mol-¹ (with respect to C5H₁2). Do not worry about how realistic the final answer is. Answer:
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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