Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
For each of the following electron-transfer reactions, speculate whether the mechanism is outer sphere or inner sphere.
![Here's the transcription of the chemical equations provided in the image, formatted for educational purposes:
---
**Chemical Reactions:**
(a) \[[IrCl_6]^{2-} + [Co(NH_3)_5(CN)]^{2+} \rightarrow [IrCl_6]^{3-} + [Co(NH_3)_5NC]^{2+}\]
(b) \[[Co(NH_3)_5(H_2O)]^{2+} + [Cr(H_2O)_6]^{2+} \rightarrow [Co(NH_3)_5(H_2O)]^{3+} + [Cr(H_2O)_6]^{2+}\]
(c) \[[*Cr(H_2O)_6]^{2+} + [W(CN)_8]^{4-} \rightarrow [Cr(H_2O)_5F]^{2+} + [W(CN)_8]^{3-}\]
**Explanation:**
- **Equation (a):** This reaction involves the exchange of ligands on cobalt and iridium complexes. The \([IrCl_6]^{2-}\) oxidizes to \([IrCl_6]^{3-}\), while the \([Co(NH_3)_5(CN)]^{2+}\) is reduced to \([Co(NH_3)_5NC]^{2+}\).
- **Equation (b):** Shows a redox reaction between cobalt and chromium complexes, where \([Co(NH_3)_5(H_2O)]^{2+}\) is oxidized to \([Co(NH_3)_5(H_2O)]^{3+}\), and \([Cr(H_2O)_6]^{2+}\) remains unchanged.
- **Equation (c):** Demonstrates a ligand exchange and redox reaction, where \([*Cr(H_2O)_6]^{2+}\) combines with \([W(CN)_8]^{4-}\) to form \([Cr(H_2O)_5F]^{2+}\) and \([W(CN)_8]^{3-}\).
Note: The asterisk (*) and arrow directions may indicate specific experimental conditions or mechanistic pathways in these reactions.
---
Please let me know if you need further explanations or illustrations!](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F73f287ec-1f7f-4342-bd76-a85a74415d84%2Fed4503c1-a9ba-4b54-88d4-10fc9e95b562%2Fs1z4tv7_processed.png&w=3840&q=75)
Transcribed Image Text:Here's the transcription of the chemical equations provided in the image, formatted for educational purposes:
---
**Chemical Reactions:**
(a) \[[IrCl_6]^{2-} + [Co(NH_3)_5(CN)]^{2+} \rightarrow [IrCl_6]^{3-} + [Co(NH_3)_5NC]^{2+}\]
(b) \[[Co(NH_3)_5(H_2O)]^{2+} + [Cr(H_2O)_6]^{2+} \rightarrow [Co(NH_3)_5(H_2O)]^{3+} + [Cr(H_2O)_6]^{2+}\]
(c) \[[*Cr(H_2O)_6]^{2+} + [W(CN)_8]^{4-} \rightarrow [Cr(H_2O)_5F]^{2+} + [W(CN)_8]^{3-}\]
**Explanation:**
- **Equation (a):** This reaction involves the exchange of ligands on cobalt and iridium complexes. The \([IrCl_6]^{2-}\) oxidizes to \([IrCl_6]^{3-}\), while the \([Co(NH_3)_5(CN)]^{2+}\) is reduced to \([Co(NH_3)_5NC]^{2+}\).
- **Equation (b):** Shows a redox reaction between cobalt and chromium complexes, where \([Co(NH_3)_5(H_2O)]^{2+}\) is oxidized to \([Co(NH_3)_5(H_2O)]^{3+}\), and \([Cr(H_2O)_6]^{2+}\) remains unchanged.
- **Equation (c):** Demonstrates a ligand exchange and redox reaction, where \([*Cr(H_2O)_6]^{2+}\) combines with \([W(CN)_8]^{4-}\) to form \([Cr(H_2O)_5F]^{2+}\) and \([W(CN)_8]^{3-}\).
Note: The asterisk (*) and arrow directions may indicate specific experimental conditions or mechanistic pathways in these reactions.
---
Please let me know if you need further explanations or illustrations!
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY