following reactions take place in the reactor: C,H,CH, + H, → CH + CH4 toluene (E benzene C,H,(CH,), + H, → C,H¿CH, + CH4 xylene (F toluene C,H,(CH,), + H, → C,H,(CH,), + CH, pseudocumene (F xylene
following reactions take place in the reactor: C,H,CH, + H, → CH + CH4 toluene (E benzene C,H,(CH,), + H, → C,H¿CH, + CH4 xylene (F toluene C,H,(CH,), + H, → C,H,(CH,), + CH, pseudocumene (F xylene
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Hydrodealkylation Process Overview**
**Hydrodealkylation** is a chemical process where side chain alkyl groups (such as methyl groups) are removed from aromatic compounds through reaction with hydrogen. The following reactions typically take place within the reactor:
1. **Toluene to Benzene Conversion**
\( \text{C}_6\text{H}_5\text{CH}_3 + \text{H}_2 \rightarrow \text{C}_6\text{H}_6 + \text{CH}_4 \)
- **Reagents:** Toluene and hydrogen
- **Products:** Benzene and methane
- **Reaction R1**
2. **Xylene to Toluene Conversion**
\( \text{C}_6\text{H}_4(\text{CH}_3)_2 + \text{H}_2 \rightarrow \text{C}_6\text{H}_5\text{CH}_3 + \text{CH}_4 \)
- **Reagents:** Xylene and hydrogen
- **Products:** Toluene and methane
- **Reaction R2**
3. **Pseudocumene to Xylene Conversion**
\( \text{C}_6\text{H}_3(\text{CH}_3)_3 + \text{H}_2 \rightarrow \text{C}_6\text{H}_4(\text{CH}_3)_2 + \text{CH}_4 \)
- **Reagents:** Pseudocumene and hydrogen
- **Products:** Xylene and methane
- **Reaction R3**
**Unwanted Side Reaction**
A side reaction can occur where two benzene molecules react, forming diphenyl:
- **Benzene to Diphenyl Reaction**
\( 2\text{C}_6\text{H}_6 \rightarrow \text{C}_{12}\text{H}_{10} + \text{H}_2 \)
- **Reagents:** Benzene
- **Products:** Diphenyl and hydrogen
- **Reaction R4**
**Process Stream Details**
- A process stream with the following composition is fed at a rate of 100 gmol/h into a hydrodealkylation plant:
- 5 mol% benzene (C₆H
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