following reactions take place in the reactor: C,H,CH, + H, → CH + CH4 toluene (E benzene C,H,(CH,), + H, → C,H¿CH, + CH4 xylene (F toluene C,H,(CH,), + H, → C,H,(CH,), + CH, pseudocumene (F xylene

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Chapter1: Chemical Foundations
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**Hydrodealkylation Process Overview**

**Hydrodealkylation** is a chemical process where side chain alkyl groups (such as methyl groups) are removed from aromatic compounds through reaction with hydrogen. The following reactions typically take place within the reactor:

1. **Toluene to Benzene Conversion**  
   \( \text{C}_6\text{H}_5\text{CH}_3 + \text{H}_2 \rightarrow \text{C}_6\text{H}_6 + \text{CH}_4 \)  
   - **Reagents:** Toluene and hydrogen
   - **Products:** Benzene and methane  
   - **Reaction R1**

2. **Xylene to Toluene Conversion**  
   \( \text{C}_6\text{H}_4(\text{CH}_3)_2 + \text{H}_2 \rightarrow \text{C}_6\text{H}_5\text{CH}_3 + \text{CH}_4 \)  
   - **Reagents:** Xylene and hydrogen
   - **Products:** Toluene and methane  
   - **Reaction R2**

3. **Pseudocumene to Xylene Conversion**  
   \( \text{C}_6\text{H}_3(\text{CH}_3)_3 + \text{H}_2 \rightarrow \text{C}_6\text{H}_4(\text{CH}_3)_2 + \text{CH}_4 \)  
   - **Reagents:** Pseudocumene and hydrogen
   - **Products:** Xylene and methane  
   - **Reaction R3**

**Unwanted Side Reaction**

A side reaction can occur where two benzene molecules react, forming diphenyl:

- **Benzene to Diphenyl Reaction**  
  \( 2\text{C}_6\text{H}_6 \rightarrow \text{C}_{12}\text{H}_{10} + \text{H}_2 \)  
  - **Reagents:** Benzene
  - **Products:** Diphenyl and hydrogen  
  - **Reaction R4**

**Process Stream Details**

- A process stream with the following composition is fed at a rate of 100 gmol/h into a hydrodealkylation plant:
  - 5 mol% benzene (C₆H
Transcribed Image Text:**Hydrodealkylation Process Overview** **Hydrodealkylation** is a chemical process where side chain alkyl groups (such as methyl groups) are removed from aromatic compounds through reaction with hydrogen. The following reactions typically take place within the reactor: 1. **Toluene to Benzene Conversion** \( \text{C}_6\text{H}_5\text{CH}_3 + \text{H}_2 \rightarrow \text{C}_6\text{H}_6 + \text{CH}_4 \) - **Reagents:** Toluene and hydrogen - **Products:** Benzene and methane - **Reaction R1** 2. **Xylene to Toluene Conversion** \( \text{C}_6\text{H}_4(\text{CH}_3)_2 + \text{H}_2 \rightarrow \text{C}_6\text{H}_5\text{CH}_3 + \text{CH}_4 \) - **Reagents:** Xylene and hydrogen - **Products:** Toluene and methane - **Reaction R2** 3. **Pseudocumene to Xylene Conversion** \( \text{C}_6\text{H}_3(\text{CH}_3)_3 + \text{H}_2 \rightarrow \text{C}_6\text{H}_4(\text{CH}_3)_2 + \text{CH}_4 \) - **Reagents:** Pseudocumene and hydrogen - **Products:** Xylene and methane - **Reaction R3** **Unwanted Side Reaction** A side reaction can occur where two benzene molecules react, forming diphenyl: - **Benzene to Diphenyl Reaction** \( 2\text{C}_6\text{H}_6 \rightarrow \text{C}_{12}\text{H}_{10} + \text{H}_2 \) - **Reagents:** Benzene - **Products:** Diphenyl and hydrogen - **Reaction R4** **Process Stream Details** - A process stream with the following composition is fed at a rate of 100 gmol/h into a hydrodealkylation plant: - 5 mol% benzene (C₆H
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