Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter8: Thermochemistry
Section: Chapter Questions
Problem 72QAP: On complete combustion at constant pressure, a 1.00-L sample of a gaseous mixture at 0C and 1.00 atm...
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Question
Report the reaction order from the Integrated Law method and include the best-fit trendline equation and R2 supporting your answer.
![Equation:
2002 [gas]
200 [gas]
02 [gas]
Thermodynamics: (@T= 3300.00 K)
Standard Enthalpy of
Formation and Entropy
A (KI/mol)
S (T) (U/mol.K)
Reaction Thermodynamics & Equilibrium Value
CO2 (gas]
-222.00
340.04
Standard enthalpy change, A.HM)
543.90
KI
Standard entropy change, AS ()
916
KI
Standard reaction free energy change
5.35
4,6°T)
Reaction free enbrgy change at initial
-5.78
277.17
KI
[pea] 0
comoosition, AGm
దీ.,6/ 1.
02 (gas]
111.45
288.93
Equillbriom constant, K
8.2293e-001
Temperature range for data
200,00-- 5000.00
Doto sources NASA
Simulated Final State: (@T = 3300.00 K; P =1.00 X)
Pressure-
1.2-
Reactants, Final
Products Composition
CO2
adjusted
Composition
Units](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff21c578f-630a-4bda-885a-34e1a76e1b04%2Ffffe8fc5-bdde-4f41-9006-9603fb221819%2Fict92gc_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Equation:
2002 [gas]
200 [gas]
02 [gas]
Thermodynamics: (@T= 3300.00 K)
Standard Enthalpy of
Formation and Entropy
A (KI/mol)
S (T) (U/mol.K)
Reaction Thermodynamics & Equilibrium Value
CO2 (gas]
-222.00
340.04
Standard enthalpy change, A.HM)
543.90
KI
Standard entropy change, AS ()
916
KI
Standard reaction free energy change
5.35
4,6°T)
Reaction free enbrgy change at initial
-5.78
277.17
KI
[pea] 0
comoosition, AGm
దీ.,6/ 1.
02 (gas]
111.45
288.93
Equillbriom constant, K
8.2293e-001
Temperature range for data
200,00-- 5000.00
Doto sources NASA
Simulated Final State: (@T = 3300.00 K; P =1.00 X)
Pressure-
1.2-
Reactants, Final
Products Composition
CO2
adjusted
Composition
Units
![Simulated Final State: (@T= 3300.00 K; P=1.00 X)
1.2-
CO2 [gas]
CO [gas)
02 (gas]
CO2 [gas] 3.8023e-001 3.5023e-001
aars moles LLitused
assolute
0.8-
0.6
Co [gas) 6.1977e-001 6.1977e-001
pars males/if
0.4
dissolved/evolved
02 [gas]
bars moles/Li
Bissoved/evoved)
3.0988e-001 3.0988e-001
0.2-
0.
Simulated Kinetics (composition over time):
Time (seconds)
Time (seccnds)
co2 [gas]
co(gas]
02 (gas)
0000 D
00320
(1.000008-00o
C.CCDCద-C00
10,00000E+00
0.00000E-000
000-200000o
8,538585-001
10,00000E-00
17.05742E-02
0.00000E+000
7.540618-001
0,00000E-000
ఉవకి పకక-నివ4.
0,00000E+00
0.2442
విరి0చ01
4.643036-00t
T00-301622 T
100-37689
000-300000 0
000-300000'0
000+3000000
10.3258
6.05015E-00
3.94585E-001
(1.974936-CO
0.00000E+000
000-300000O
000+300000
10.4071
5.506836-001
0,00000E-000
0,00000E-00
12.246598-001
0.00000E-00D
0.4886
494740E-001
2.473706-001
0,000006-000
000-300000 O
0.5710
18:32824E-001
2,65812E-001
0.00000E-000
000 200000O
c00-300000.0
0.5509
633946E-00
10,00000E-00
(0,00000E-00o
5.66054E-00L
0.00000E-00
0.7344
12,0:580E-001
15.35420E-00L
0,000005-30
000-300000 e
c00+300000o
0.8133
3.50234E-001
16.497688-001
3.09383E-00
5.00020E-0e
000 300000 0
000+300000
Reactant
Half Life (seconds)
Conc./Press. (moles/L or bar=)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff21c578f-630a-4bda-885a-34e1a76e1b04%2Ffffe8fc5-bdde-4f41-9006-9603fb221819%2Fef7dhh_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Simulated Final State: (@T= 3300.00 K; P=1.00 X)
1.2-
CO2 [gas]
CO [gas)
02 (gas]
CO2 [gas] 3.8023e-001 3.5023e-001
aars moles LLitused
assolute
0.8-
0.6
Co [gas) 6.1977e-001 6.1977e-001
pars males/if
0.4
dissolved/evolved
02 [gas]
bars moles/Li
Bissoved/evoved)
3.0988e-001 3.0988e-001
0.2-
0.
Simulated Kinetics (composition over time):
Time (seconds)
Time (seccnds)
co2 [gas]
co(gas]
02 (gas)
0000 D
00320
(1.000008-00o
C.CCDCద-C00
10,00000E+00
0.00000E-000
000-200000o
8,538585-001
10,00000E-00
17.05742E-02
0.00000E+000
7.540618-001
0,00000E-000
ఉవకి పకక-నివ4.
0,00000E+00
0.2442
విరి0చ01
4.643036-00t
T00-301622 T
100-37689
000-300000 0
000-300000'0
000+3000000
10.3258
6.05015E-00
3.94585E-001
(1.974936-CO
0.00000E+000
000-300000O
000+300000
10.4071
5.506836-001
0,00000E-000
0,00000E-00
12.246598-001
0.00000E-00D
0.4886
494740E-001
2.473706-001
0,000006-000
000-300000 O
0.5710
18:32824E-001
2,65812E-001
0.00000E-000
000 200000O
c00-300000.0
0.5509
633946E-00
10,00000E-00
(0,00000E-00o
5.66054E-00L
0.00000E-00
0.7344
12,0:580E-001
15.35420E-00L
0,000005-30
000-300000 e
c00+300000o
0.8133
3.50234E-001
16.497688-001
3.09383E-00
5.00020E-0e
000 300000 0
000+300000
Reactant
Half Life (seconds)
Conc./Press. (moles/L or bar=)
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