Find the oxidation number of: A. chlorine in ClO4- ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7) B. manganese in MnO4- ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7) C. cobalt in Co ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7)   Find the oxidation number of: A. iron in Fe(OH)2 ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7) B. nickel in Ni ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7) C. manganese in MnO4-

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Find the oxidation number of:

A. chlorine in ClO4- ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7)
B. manganese in MnO4- ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7)
C. cobalt in Co ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7)

 

Find the oxidation number of:

A. iron in Fe(OH)2 ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7)
B. nickel in Ni ___(-7-6-5-4-3-2-10+1+2+3+4+5+6+7)
C. manganese in MnO4-

 

Expert Solution
Step 1

The sum of oxidation number of all the atoms present in any anion = charge on the anion 

 

Step 2

A) chlorine in ClO4- 

Since O will be having -2 oxidation number as it has 6 valence electron and needs 2 electron to complete octet ( O  can not expand its octet due to non availability of vacant d orbitals )

Assuming the oxidation number of Cl is y 

Hence y + (-2) X 4 = Oxidation number of Cl + oxidation number of O X 4 = charge on ion = -1

Hence y -8 = -1

=> y = oxidation number of Cl = +7

Step 3

B) manganese in MnO4-

Since O will be having -2 oxidation number as it has 6 valence electron and needs 2 electron to complete octet ( O  can not expand its octet due to non availability of vacant d orbitals )

Assuming the oxidation number of Mn is y 

Hence y + (-2) X 4 = Oxidation number of Mn + oxidation number of O X 4 = charge on ion = -1

Hence y -8 = -1

=> y = oxidation number of Mn = +7

Step 4

C) cobalt in Co

Assuming the oxidation number of Mn is y 

Hence y = Oxidation number of Mn = charge on ion = 0

Hence y = 0

=> y = oxidation number of Co = 0

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