a) Cr.0,2- + Fe* → Fe3* + Cr3+ (in acidic solution) b) Mn* + BiO3 → MnOq¯ + Bi³* (in acidic solution) c) HSO3 + MnO4¯ → HSO4¯+ Mn²* (in acidic solution)
a) Cr.0,2- + Fe* → Fe3* + Cr3+ (in acidic solution) b) Mn* + BiO3 → MnOq¯ + Bi³* (in acidic solution) c) HSO3 + MnO4¯ → HSO4¯+ Mn²* (in acidic solution)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Oxidation Number Assignment and Equation Balancing
1. **Objective**: Assign oxidation numbers to each element in the following reactions and balance the equations.
---
#### a) Reaction in Acidic Solution
\[ \text{Cr}_2\text{O}_7^{2-} + \text{Fe}^{2+} \rightarrow \text{Fe}^{3+} + \text{Cr}^{3+} \]
---
#### b) Reaction in Acidic Solution
\[ \text{Mn}^{2+} + \text{BiO}_3^- \rightarrow \text{MnO}_4^- + \text{Bi}^{3+} \]
---
#### c) Reaction in Acidic Solution
\[ \text{HSO}_3^- + \text{MnO}_4^- \rightarrow \text{HSO}_4^- + \text{Mn}^{2+} \]
---
#### d) Reaction in Basic Solution
\[ \text{H}_2\text{O}_2 + \text{ClO}_2 \rightarrow \text{ClO}_2^- + \text{O}_2 \]
---
#### e) Reaction in Basic Solution
\[ \text{Cl}_2 \rightarrow \text{ClO}_2^- + \text{Cl}^- \]
---
#### f) Reaction in Acidic Solution
\[ \text{MnO}_4^- + \text{H}_2\text{C}_2\text{O}_4 \rightarrow \text{CO}_2 + \text{Mn}^{2+} \]
---
### Explanation for Students
- **Oxidation Numbers**: Determine the oxidation state of each element in the reactants and products.
- **Balancing Equations**: Ensure that atoms and charges are balanced on both sides of the equation, considering the medium (acidic or basic).
- **Acidic and Basic Solutions**: Note that balancing may require adding H⁺ in acidic solutions and OH⁻ in basic solutions to achieve a balance in hydrogen and oxygen atoms.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F85a2fef8-75c6-4f70-afce-e76c8de2cc0b%2F1a11a427-4e08-4a13-a7e7-4689c0f11f72%2Fkba7gvr_processed.png&w=3840&q=75)
Transcribed Image Text:### Oxidation Number Assignment and Equation Balancing
1. **Objective**: Assign oxidation numbers to each element in the following reactions and balance the equations.
---
#### a) Reaction in Acidic Solution
\[ \text{Cr}_2\text{O}_7^{2-} + \text{Fe}^{2+} \rightarrow \text{Fe}^{3+} + \text{Cr}^{3+} \]
---
#### b) Reaction in Acidic Solution
\[ \text{Mn}^{2+} + \text{BiO}_3^- \rightarrow \text{MnO}_4^- + \text{Bi}^{3+} \]
---
#### c) Reaction in Acidic Solution
\[ \text{HSO}_3^- + \text{MnO}_4^- \rightarrow \text{HSO}_4^- + \text{Mn}^{2+} \]
---
#### d) Reaction in Basic Solution
\[ \text{H}_2\text{O}_2 + \text{ClO}_2 \rightarrow \text{ClO}_2^- + \text{O}_2 \]
---
#### e) Reaction in Basic Solution
\[ \text{Cl}_2 \rightarrow \text{ClO}_2^- + \text{Cl}^- \]
---
#### f) Reaction in Acidic Solution
\[ \text{MnO}_4^- + \text{H}_2\text{C}_2\text{O}_4 \rightarrow \text{CO}_2 + \text{Mn}^{2+} \]
---
### Explanation for Students
- **Oxidation Numbers**: Determine the oxidation state of each element in the reactants and products.
- **Balancing Equations**: Ensure that atoms and charges are balanced on both sides of the equation, considering the medium (acidic or basic).
- **Acidic and Basic Solutions**: Note that balancing may require adding H⁺ in acidic solutions and OH⁻ in basic solutions to achieve a balance in hydrogen and oxygen atoms.
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