Fill in the blanks for the equilibrium of the reactants A+B with the products C+D. The temperature is 310K. When considering this table, it will be useful to know that the precision of the numbers provided is no better than ± 0.1 kJ/mole

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

Fill in the blanks for the equilibrium of the reactants A+B with the products C+D. The temperature is 310K. When considering this table, it will be useful to know that the precision of the numbers provided is no better than ± 0.1 kJ/mole.

 

 

### Thermodynamic Data Table

This table provides information about the thermodynamics of a reaction involving four components: [A], [B], [C], and [D]. Each row represents a different condition with varying concentrations of these components.

#### Column Descriptions:

- **[A], [B], [C], [D]**: The concentrations of components A, B, C, and D, respectively. These are given in molarity (M) or millimolarity (mM, µM).

- **ΔG°' (kJ mol⁻¹ K⁻¹)**: The standard Gibbs free energy change of the reaction. This value indicates whether the reaction is spontaneous under standard conditions.

- **ΔG' (kJ mol⁻¹ K⁻¹)**: The Gibbs free energy change under the specific conditions of the row. This value can differ from ΔG°' due to the non-standard concentrations of reactants and products.

- **At Equilibrium?**: Indicates whether the reaction is at equilibrium under the given conditions. A reaction at equilibrium will not show net change in the concentrations of reactants and products over time.

- **Direction Favorable?**: Indicates if the reaction is thermodynamically favorable in the forward direction under the given conditions.

#### Row Descriptions:

1. **Row 1**:
   - [A], [B], [C], [D] = 1 M, 1 M, 1 M, 1 M
   - ΔG°' = -20.0 kJ mol⁻¹ K⁻¹, ΔG' = -20.0 kJ mol⁻¹ K⁻¹
   - At Equilibrium: No
   - Direction Favorable: Yes

2. **Row 2**:
   - [A], [B], [C], [D] = 2 mM, 1 mM, 0.0135 M, 50 mM
   - ΔG°' = ?, ΔG' = 30.0 kJ mol⁻¹ K⁻¹
   - At Equilibrium: No
   - Direction Favorable: No

3. **Row 3**:
   - [A], [B], [C], [D] = 2 mM, 1 mM, 0.001 M, 50 mM
   - Δ
Transcribed Image Text:### Thermodynamic Data Table This table provides information about the thermodynamics of a reaction involving four components: [A], [B], [C], and [D]. Each row represents a different condition with varying concentrations of these components. #### Column Descriptions: - **[A], [B], [C], [D]**: The concentrations of components A, B, C, and D, respectively. These are given in molarity (M) or millimolarity (mM, µM). - **ΔG°' (kJ mol⁻¹ K⁻¹)**: The standard Gibbs free energy change of the reaction. This value indicates whether the reaction is spontaneous under standard conditions. - **ΔG' (kJ mol⁻¹ K⁻¹)**: The Gibbs free energy change under the specific conditions of the row. This value can differ from ΔG°' due to the non-standard concentrations of reactants and products. - **At Equilibrium?**: Indicates whether the reaction is at equilibrium under the given conditions. A reaction at equilibrium will not show net change in the concentrations of reactants and products over time. - **Direction Favorable?**: Indicates if the reaction is thermodynamically favorable in the forward direction under the given conditions. #### Row Descriptions: 1. **Row 1**: - [A], [B], [C], [D] = 1 M, 1 M, 1 M, 1 M - ΔG°' = -20.0 kJ mol⁻¹ K⁻¹, ΔG' = -20.0 kJ mol⁻¹ K⁻¹ - At Equilibrium: No - Direction Favorable: Yes 2. **Row 2**: - [A], [B], [C], [D] = 2 mM, 1 mM, 0.0135 M, 50 mM - ΔG°' = ?, ΔG' = 30.0 kJ mol⁻¹ K⁻¹ - At Equilibrium: No - Direction Favorable: No 3. **Row 3**: - [A], [B], [C], [D] = 2 mM, 1 mM, 0.001 M, 50 mM - Δ
Expert Solution
steps

Step by step

Solved in 7 steps with 2 images

Blurred answer
Knowledge Booster
Chemical Equilibrium
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY