FIGURE 23.7 Steps in the Citric Acid Cycle CH3-C-SCOA HSCOA CO2 ÇO2 CH2 1) NADH + H+ C=0 HO-C-CO2 H20 CH2 CH, 8 oxaloacetate 2 citrate NAD+. (CH2 H-C-CO2 Но -С—н НО -С—Н CH2 CO2 CO2 isocitrate malate NAD+ 3 CO2. 7 H20 ÇO2 NADH + H+ ÇO2 CH HSCOACH2 CO2 HC CO2 C=0 HSCOA ÇO2 CH2 NAD+ CO2- a-ketoglutarate fumarate 5 CH2 FADH2 CH2 FAD CH2 GDP NADH + H+ GTP C=0 succinate SCOA SUccinyl COA

General, Organic, and Biological Chemistry
7th Edition
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:H. Stephen Stoker
Chapter24: Carbohydrate Metabolism
Section: Chapter Questions
Problem 24.30EP
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Which intermediate(s) in the citric acid cycle contain one chirality center? Which intermediate(s) contain a tertiary alcohol? 

FIGURE 23.7 Steps in the Citric Acid Cycle
CH3-C-SCOA HSCOA
CO2
CH2
NADH + H+ C=0
HO-C-CO2
H20
CH2
CH2
CO2
2
citrate
8 oxaloacetate
ÇO2
NAD+
CH2
H-C-CO2
Но-с—н
НО -С—Н
CH2
CO,
isocitrate
malate
NAD+
7 H20
CO2-
ÇO2
NADH + H+
CH2
CH
HSCOA CH2
CO2
4
96)
C=0
HSCOA
CH2
NAD+ CO2-
a-ketoglutarate
fumarate
CH2
FADH2
CH2
CH2
GDP
FAD
NADH + H+
CO2 GTP
C=0
succinate
SCOA
succinyl CoA
Transcribed Image Text:FIGURE 23.7 Steps in the Citric Acid Cycle CH3-C-SCOA HSCOA CO2 CH2 NADH + H+ C=0 HO-C-CO2 H20 CH2 CH2 CO2 2 citrate 8 oxaloacetate ÇO2 NAD+ CH2 H-C-CO2 Но-с—н НО -С—Н CH2 CO, isocitrate malate NAD+ 7 H20 CO2- ÇO2 NADH + H+ CH2 CH HSCOA CH2 CO2 4 96) C=0 HSCOA CH2 NAD+ CO2- a-ketoglutarate fumarate CH2 FADH2 CH2 CH2 GDP FAD NADH + H+ CO2 GTP C=0 succinate SCOA succinyl CoA
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