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ff. 2 equivalents of methyl ethanoate + sodium methoxide in methanol 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED The Nucleophile is Potential to Establish a Resonance System Option 1: Almost all reactions +CH- Option 2: When Nu is a strong base ( OH or OR), and the leaving group is identical to the Nu 1 (Preferred) (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is remove the alpha hydrogen and create a resonance-stabilized carbanion that can act as a nucleophile.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: Always use UNLESS Option 2: The Nu matches Y AND is -OR 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O) (option 1 is reform the double bond) (option 2 is add a hydrogen ion) * If you reform the Double bond Whots the - Leau ing group? - Shells? electronegativity? Circle the option and reason Reason? Option 1: Always use UNLESS Ew A/ Rensone? Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that charge just added, AND it is N or O. 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)

ff. 2 equivalents of methyl ethanoate + sodium methoxide in methanol 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED The Nucleophile is Potential to Establish a Resonance System Option 1: Almost all reactions +CH- Option 2: When Nu is a strong base ( OH or OR), and the leaving group is identical to the Nu 1 (Preferred) (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is remove the alpha hydrogen and create a resonance-stabilized carbanion that can act as a nucleophile.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: Always use UNLESS Option 2: The Nu matches Y AND is -OR 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O) (option 1 is reform the double bond) (option 2 is add a hydrogen ion) * If you reform the Double bond Whots the - Leau ing group? - Shells? electronegativity? Circle the option and reason Reason? Option 1: Always use UNLESS Ew A/ Rensone? Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that charge just added, AND it is N or O. 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(Hex-4-en-3-one+CH3CH2MgBR). It's complete. Please follow directions. 

ff. 2 equivalents of methyl ethanoate + sodium methoxide in methanol 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED The Nucleophile is Potential to Establish a Resonance System Option 1: Almost all reactions CH- Option 2: When Nu is a strong base (OH or OR), 1 (Preferred) and the leaving group is identical to the Nu (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is remove the alpha hydrogen and create a resonance-stabilized carbanion that can act as a nucleophile.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: Always use UNLESS Option 2: The Nu matches Y AND is -OR 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, R- or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) * if you reform the Double bond Whots tle - LeGu ing group? - Shells ? elec tronegativity? Circle the option and reason Reason? Option 1: Always use UNLESS Ew A/ ReAsonle? Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that just added, AND it is N or O. charge ? 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
Transcribed Image Text:ff. 2 equivalents of methyl ethanoate + sodium methoxide in methanol 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED The Nucleophile is Potential to Establish a Resonance System Option 1: Almost all reactions CH- Option 2: When Nu is a strong base (OH or OR), 1 (Preferred) and the leaving group is identical to the Nu (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is remove the alpha hydrogen and create a resonance-stabilized carbanion that can act as a nucleophile.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: Always use UNLESS Option 2: The Nu matches Y AND is -OR 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, R- or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) * if you reform the Double bond Whots tle - LeGu ing group? - Shells ? elec tronegativity? Circle the option and reason Reason? Option 1: Always use UNLESS Ew A/ ReAsonle? Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that just added, AND it is N or O. charge ? 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
CH3 -CH 2CH=cH-CHz z. hex-4-en-3-one + CH3CH2MgBr 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED CH- CH2 The Nucleophile is CH3- CH = ě - cH = CH;-CHts Resonance System Option 1: Only the Nu created from RMgBr, NaBH or LIAIH, sticks R R-CH CH 8+ Option 2 All other Nu end up here eventually 1 (Preferred) NUB CHg-CH, (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is to react the electron-rich nucleophile with the slightly electron-deficient carbon at the end of the resonance system.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: RMgBr, LIAIH4, or NaBH4 Option 2: All other Nu end up sticking here 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex :0:a Ht - CH-CH-CH3 CH2-CH3 Option 1 (Prefered). All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS * if u reform the DOuble bond you Option 2: There is no leaving group (there are whots tle Reason? carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that Ew A/ ReaSonae? - LeGuing group? - Shells ? elec trinegativity? just added, AND it is N or O. | charge 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
Transcribed Image Text:CH3 -CH 2CH=cH-CHz z. hex-4-en-3-one + CH3CH2MgBr 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED CH- CH2 The Nucleophile is CH3- CH = ě - cH = CH;-CHts Resonance System Option 1: Only the Nu created from RMgBr, NaBH or LIAIH, sticks R R-CH CH 8+ Option 2 All other Nu end up here eventually 1 (Preferred) NUB CHg-CH, (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is to react the electron-rich nucleophile with the slightly electron-deficient carbon at the end of the resonance system.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: RMgBr, LIAIH4, or NaBH4 Option 2: All other Nu end up sticking here 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex :0:a Ht - CH-CH-CH3 CH2-CH3 Option 1 (Prefered). All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS * if u reform the DOuble bond you Option 2: There is no leaving group (there are whots tle Reason? carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that Ew A/ ReaSonae? - LeGuing group? - Shells ? elec trinegativity? just added, AND it is N or O. | charge 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
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