Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Complete the following reactions: indicate the mechanism (SN1 or SN2). If the reaction does not proceed, indicate so and the reason as to why it would not.
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#### Chemical Reaction 1
- **Reactant**: 2-Iodopropane (Isopropyl iodide)
- **Reagent**: Potassium cyanide (KCN)
- **Solvent**: Acetonitrile (CH₃CN)
- **Reaction Type**: Nucleophilic substitution
In this reaction, 2-iodopropane is treated with KCN in acetonitrile, leading to the substitution of the iodide ion by a cyanide ion, forming isopropyl cyanide.
#### Chemical Reaction 2
- **Reactant**: 4-Tosyloxymethyl-1-methylcyclohexane
- **Reagent**: Methanol (CH₃OH)
- **Reaction Type**: Nucleophilic substitution
In this reaction, the reactant has a tosylate leaving group (OTs), which when interacting with methanol, results in the substitution reaction where the tosylate group is replaced by a methoxy group. This typically results in the formation of the ether.
**Note**: These reactions illustrate typical SN2 and SN1 mechanisms, depending on factors like substrate structure and reaction conditions.
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