Explaining Vapor Pressure in Terms of IMFs Given the shown structural formulas for these four compounds, explain their relative vapor pressures in terms of types and extents of IMFs: OH I H₂C-CH₂ ethanol HO OH | | H₂C-CH₂ ethylene glycol CH3-CH₂-O-CH₂-CH3 and H-O-H diethyl ether water

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Explaining Vapor Pressure in Terms of IMFs
Given the shown structural formulas for these four compounds, explain their relative vapor pressures in
terms of types and extents of IMFs:
OH
I
H₂C-CH₂
ethanol
HO
OH
| |
H₂C-CH₂
ethylene glycol
Solution
CH₂CH₂OH: H-bonding & LDF.
CH₂OHCH₂OH: Stronger H-bonding than ethanol (also LDF), and higher MM than H₂O.
More viscous than ethanol, thus quite a low P
vap.
CH3-CH₂-0-CH₂ CH3 and H-O-H
diethyl ether
water
C4H₁0O: Dispersion forces AND dipole-dipole. Diethylether is quite a volatile
substance, with quite a high Pvap:
vap•
H₂O: H-bonding & LDF. Although the molecule with the LOWEST Molar Mass, it has
Of the choices above, ONLY ethylene glycol has a LOWER Pvap-
a low Pvap.
LOWEST Pvap
HIGHEST Pvap
<diethyl ether
ethylene glycol <
H₂O
< CH₂CH₂OH
Transcribed Image Text:Explaining Vapor Pressure in Terms of IMFs Given the shown structural formulas for these four compounds, explain their relative vapor pressures in terms of types and extents of IMFs: OH I H₂C-CH₂ ethanol HO OH | | H₂C-CH₂ ethylene glycol Solution CH₂CH₂OH: H-bonding & LDF. CH₂OHCH₂OH: Stronger H-bonding than ethanol (also LDF), and higher MM than H₂O. More viscous than ethanol, thus quite a low P vap. CH3-CH₂-0-CH₂ CH3 and H-O-H diethyl ether water C4H₁0O: Dispersion forces AND dipole-dipole. Diethylether is quite a volatile substance, with quite a high Pvap: vap• H₂O: H-bonding & LDF. Although the molecule with the LOWEST Molar Mass, it has Of the choices above, ONLY ethylene glycol has a LOWER Pvap- a low Pvap. LOWEST Pvap HIGHEST Pvap <diethyl ether ethylene glycol < H₂O < CH₂CH₂OH
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Phase Diagrams
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY