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Explain why aniline (on the left; pK, = 9.13) is a stronger base than cyclohexylamine (on the right; pKp = 3.3). Use appropriate structures in your explanation. NH2 NH2

Explain why aniline (on the left; pK, = 9.13) is a stronger base than cyclohexylamine (on the right; pKp = 3.3). Use appropriate structures in your explanation. NH2 NH2

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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ELECTRONEGATIVITY VALUES OF THE ELEMENTS H 2.1 eg 1.5 N ON 2.0 2.5 3.0 3.5 4.0 Na IS 6'0 1.2 1.5 1.8 2.1 2.5 :に Ca Sc Mn Fe uz Ga Ge SV Se Br IN 1.9 1.6 1.6 1.8 2.0 2.4 2.8 0.8 1.3 1.5 1.6 1.6 1.5 1.8 6'1 Sr ex I 1 as us u po by Pd vu na 1 0ow aN zA 0.8 1.2 1.8 2.2 2.2 2.2 61 1.7 1.7 1.8 1.9 2.1 2.5 Re B7 1.1 1.3 Ta SO 2.2 2.2 ny 2.4 BH 6'1 1.8 At od 2.2 18 0.7 0.9 1.5 1.7 2.2 1.9 2.0 6'1 Acid Acid eyd HO HƆ 10.3 CH3CH3 15.5 CH3CH2NH2 | 36 H2C=CH2 44 CH3SH HCN 9.31 25 HF 3.2 EHN 15.7 9.25 HCI "HN - -1.7 10.6 HN°HƆ -10 +O°H IH CH3COOH 4.8
Transcribed Image Text:ELECTRONEGATIVITY VALUES OF THE ELEMENTS H 2.1 eg 1.5 N ON 2.0 2.5 3.0 3.5 4.0 Na IS 6'0 1.2 1.5 1.8 2.1 2.5 :に Ca Sc Mn Fe uz Ga Ge SV Se Br IN 1.9 1.6 1.6 1.8 2.0 2.4 2.8 0.8 1.3 1.5 1.6 1.6 1.5 1.8 6'1 Sr ex I 1 as us u po by Pd vu na 1 0ow aN zA 0.8 1.2 1.8 2.2 2.2 2.2 61 1.7 1.7 1.8 1.9 2.1 2.5 Re B7 1.1 1.3 Ta SO 2.2 2.2 ny 2.4 BH 6'1 1.8 At od 2.2 18 0.7 0.9 1.5 1.7 2.2 1.9 2.0 6'1 Acid Acid eyd HO HƆ 10.3 CH3CH3 15.5 CH3CH2NH2 | 36 H2C=CH2 44 CH3SH HCN 9.31 25 HF 3.2 EHN 15.7 9.25 HCI "HN - -1.7 10.6 HN°HƆ -10 +O°H IH CH3COOH 4.8
Explain why aniline (on the left; pK, = 9.13) is a stronger base than cyclohexylamine (on the right; pK, = 3.3). Use appropriate structures in your explanation. NH2 NH2
Transcribed Image Text:Explain why aniline (on the left; pK, = 9.13) is a stronger base than cyclohexylamine (on the right; pK, = 3.3). Use appropriate structures in your explanation. NH2 NH2
Expert Solution
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Amines are basic in nature due to their ability to donate lone pair of electrons present on nitrogen. Basic strength refers to ease of release of electrons.

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