EXERCISE ON EXTERNAL AND INTERNAL STANDARD METHODS Potassium can be determined by spectrometry using a lithium internal standard. The following data were obtained for standard solutions of KCI and an unknown containing a constant, known amount of LICI as the internal standard. Concentration (ppm) 1.0 Intensity of Kemission Intensity of Li emission 10.0 10.0 2.0 15.3 7.5 5.0 34.7 6.8 7.5 65.2 8.5 10.0 95.8 10.0 20.0 110.2 5.8 Unknown sample 47.3 9.1 Using the external standard method: a. Plot the Kemission intensity vs. the concentration of K, and determine the equation of the line, slope and y-intercept. un co n

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
EXERCISE ON EXTERNAL AND INTERNAL STANDARD METHODS
Potassium can be determined by spectrometry using a lithium internal standard. The following data
were obtained for standard solutions of KCI and an unknown containing a constant, known amount
of LiCl as the internal standard.
Concentration (ppm)
Intensity of K emission
Intensity of Li emission
1.0
10.0
10.0
2.0
15.3
7.5
5.0
34.7
6.8
7.5
65.2
8.5
10.0
95.8
10.0
20.0
110.2
5.8
Unknown sample
47.3
9.1
Using the external standard method:
a. Plot the Kemission intensity vs. the concentration of K, and determine the equation of the
line, slope and y-intercept.
Using the internal standard method:
a. Plot the ratio of the K intensity to the Li intensity vs. the concentration of K, and determine
the equation of the line, slope and y-intercept.
b. Why does the internal standard improve linearity?
C.
Calculate the concentration of K in the unknown sample.
Transcribed Image Text:EXERCISE ON EXTERNAL AND INTERNAL STANDARD METHODS Potassium can be determined by spectrometry using a lithium internal standard. The following data were obtained for standard solutions of KCI and an unknown containing a constant, known amount of LiCl as the internal standard. Concentration (ppm) Intensity of K emission Intensity of Li emission 1.0 10.0 10.0 2.0 15.3 7.5 5.0 34.7 6.8 7.5 65.2 8.5 10.0 95.8 10.0 20.0 110.2 5.8 Unknown sample 47.3 9.1 Using the external standard method: a. Plot the Kemission intensity vs. the concentration of K, and determine the equation of the line, slope and y-intercept. Using the internal standard method: a. Plot the ratio of the K intensity to the Li intensity vs. the concentration of K, and determine the equation of the line, slope and y-intercept. b. Why does the internal standard improve linearity? C. Calculate the concentration of K in the unknown sample.
Expert Solution
steps

Step by step

Solved in 3 steps with 1 images

Blurred answer
Knowledge Booster
Electroanalytical Techniques
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY