Exercise 6. The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics of the aqueous reaction was observed several times at the same temperature: Mn²+ 2 Ce (aq) + TI+(aq) - 2 Ce³+ (aq) + T1³+ (aq) Initial rate of formation Experiment [Ce4+] initial [TI*]initial [Mn²+] of T1³+ (M s-¹) 1 0.0050 0.0025 0.0010 2.0 × 10-4 2 0.0050 0.0050 0.0010 2.0 × 10-4 3 0.0100 0.0025 0.0010 4.0 × 10-4 4 0.0050 0.0050 0.0030 6.0 × 10-4 a. Determine the rate orders with respect to Ce4+, to TI+, and to Mn2+ and explain or show how you arrived at your answers. Work/Explanation: i. The order with respect to Ce¹¹ is Work/Explanation: ii. The order with respect to Tl is, Page 4 of 9

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6.
The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics
of the aqueous reaction was observed several times at the same temperature:
Mn²+
2 Ceª (aq) + TI+(aq) -- 2 Ce³+ (aq) + T1³+ (aq)
Initial rate of formation
[TI] initial
Experiment
[Ce4+] initial
[Mn²+]
of T1³+ (M s-¹)
0.0050
0.0025
0.0010
2.0 × 10-4
0.0050
0.0050
0.0010
2.0 × 10-4
0.0100
0.0025
0.0010
4.0 × 10-4
0.0050
0.0050-
0.0030
6.0 × 10-4
a. Determine the rate orders with respect to Ce4+, to TI*, and to Mn²+ and explain or show how you
arrived at your answers.
Work/Explanation:
1. The order with respect to Cet is
Work/Explanation:
ii. The order with respect to This
Page 4 of
AWNE
1
2
3
4
Transcribed Image Text:Exercise 6. The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics of the aqueous reaction was observed several times at the same temperature: Mn²+ 2 Ceª (aq) + TI+(aq) -- 2 Ce³+ (aq) + T1³+ (aq) Initial rate of formation [TI] initial Experiment [Ce4+] initial [Mn²+] of T1³+ (M s-¹) 0.0050 0.0025 0.0010 2.0 × 10-4 0.0050 0.0050 0.0010 2.0 × 10-4 0.0100 0.0025 0.0010 4.0 × 10-4 0.0050 0.0050- 0.0030 6.0 × 10-4 a. Determine the rate orders with respect to Ce4+, to TI*, and to Mn²+ and explain or show how you arrived at your answers. Work/Explanation: 1. The order with respect to Cet is Work/Explanation: ii. The order with respect to This Page 4 of AWNE 1 2 3 4
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