Exercise6.The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kineticsof the aqueous reaction was observed several times at the same temperature:Mn²+2 Ceª (aq) + TI+(aq) -- 2 Ce³+ (aq) + T1³+ (aq)Initial rate of formation[TI] initialExperiment[Ce4+] initial[Mn²+]of T1³+ (M s-¹)0.00500.00250.00102.0 × 10-40.00500.00500.00102.0 × 10-40.01000.00250.00104.0 × 10-40.00500.0050-0.00306.0 × 10-4a. Determine the rate orders with respect to Ce4+, to TI*, and to Mn²+ and explain or show how youarrived at your answers.Work/Explanation:1. The order with respect to Cet isWork/Explanation:ii. The order with respect to ThisPage 4 ofAWNE1234

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Exercise 6. The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics of the aqueous reaction was observed several times at the same temperature: Mn²+ 2 Ce (aq) + TI+(aq) - 2 Ce³+ (aq) + T1³+ (aq) Initial rate of formation Experiment [Ce4+] initial [TI*]initial [Mn²+] of T1³+ (M s-¹) 1 0.0050 0.0025 0.0010 2.0 × 10-4 2 0.0050 0.0050 0.0010 2.0 × 10-4 3 0.0100 0.0025 0.0010 4.0 × 10-4 4 0.0050 0.0050 0.0030 6.0 × 10-4 a. Determine the rate orders with respect to Ce4+, to TI+, and to Mn2+ and explain or show how you arrived at your answers. Work/Explanation: i. The order with respect to Ce¹¹ is Work/Explanation: ii. The order with respect to Tl is, Page 4 of 9

Exercise 6. The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics of the aqueous reaction was observed several times at the same temperature: Mn²+ 2 Ce (aq) + TI+(aq) - 2 Ce³+ (aq) + T1³+ (aq) Initial rate of formation Experiment [Ce4+] initial [TI*]initial [Mn²+] of T1³+ (M s-¹) 1 0.0050 0.0025 0.0010 2.0 × 10-4 2 0.0050 0.0050 0.0010 2.0 × 10-4 3 0.0100 0.0025 0.0010 4.0 × 10-4 4 0.0050 0.0050 0.0030 6.0 × 10-4 a. Determine the rate orders with respect to Ce4+, to TI+, and to Mn2+ and explain or show how you arrived at your answers. Work/Explanation: i. The order with respect to Ce¹¹ is Work/Explanation: ii. The order with respect to Tl is, Page 4 of 9

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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