Exercise 1 *Problem 4.2 Use separation of variables in cartesian coordinates to solve the infinite cubical well (or "particle in a box"): 0, if x.y. z are all between 0 and a: 0o, otherwise. (x. y. z) = (a) Find the stationary states, and the corresponding energies. (b) Call the distinct energies E1. E2. E3, .., in order of increasing energy. Find E1. E2. E3, E4. Es, and E6. Determine their degeneracies (that is, the number of different states that share the same energy). Comment: In one dimension degenerate bound states do not occur (see Problem 2.45), but in three dimensions they are very common. (c) What is the degeneracy of E14, and why is this case interesting?

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Homework #1
Quantum Mechanics 2
Due: 23/2/1400
Exercise 1
*Problem 4.2 Use separation of variables in cartesian coordinates to solve the
infinite cubical well (or "particle in a box"):
0, if x. y.z are all between 0 and a;
o, otherwise.
V(x. y. z) =
(a) Find the stationary states, and the corresponding energies.
(b) Call the distinct energies E1. E2. E3, ..., in order of increasing energy.
Find E1. E2. E3, E4. Es, and E6. Determine their degeneracies (that is, the
number of different states that share the same energy). Comment: In one
dimension degenerate bound states do not occur (see Problem 2.45), but in
three dimensions they are very common.
(c) What is the degeneracy of E14. and why is this case interesting?
Exercise 2
*Problem 4.13
(a) Find (r) and (r2) for an electron in the ground state of hydrogen. Express
your answers in terms of the Bohr radius.
(b) Find (x) and (x2) for an electron in the ground state of hydrogen. Hint: This
requires no new integration-note that r? = x? + y? + z?, and exploit the
symmetry of the ground state.
(c) Find (r2) in the state n 2, 1 = 1, m 1. Warning: This state is not
symmetrical in x, y, z. Use x =r sin e cos o.
Exercise 3
Problem 4.14 What is the most probable value of r, in the ground state of hydro-
gen? (The answer is not zero!) Hint: First you must figure out the probability that
the electron would be found between r and r+dr.
Transcribed Image Text:Homework #1 Quantum Mechanics 2 Due: 23/2/1400 Exercise 1 *Problem 4.2 Use separation of variables in cartesian coordinates to solve the infinite cubical well (or "particle in a box"): 0, if x. y.z are all between 0 and a; o, otherwise. V(x. y. z) = (a) Find the stationary states, and the corresponding energies. (b) Call the distinct energies E1. E2. E3, ..., in order of increasing energy. Find E1. E2. E3, E4. Es, and E6. Determine their degeneracies (that is, the number of different states that share the same energy). Comment: In one dimension degenerate bound states do not occur (see Problem 2.45), but in three dimensions they are very common. (c) What is the degeneracy of E14. and why is this case interesting? Exercise 2 *Problem 4.13 (a) Find (r) and (r2) for an electron in the ground state of hydrogen. Express your answers in terms of the Bohr radius. (b) Find (x) and (x2) for an electron in the ground state of hydrogen. Hint: This requires no new integration-note that r? = x? + y? + z?, and exploit the symmetry of the ground state. (c) Find (r2) in the state n 2, 1 = 1, m 1. Warning: This state is not symmetrical in x, y, z. Use x =r sin e cos o. Exercise 3 Problem 4.14 What is the most probable value of r, in the ground state of hydro- gen? (The answer is not zero!) Hint: First you must figure out the probability that the electron would be found between r and r+dr.
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