(e) Find the ratio of the equilibrium positions and the frequencies of the small oscillations between the cases λ = 10 and X= 14. That is req(λ = 14)/reg(λ: 10), and fosc (X= 14)/ fosc (λ = 10). Hint: the ratio of the equilibrium positions differs from 1 by about 2%, whereas the the ratio of the two frequencies differs from 1 by about 54%!

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help me with part e please

The vibrational properties of a diatomic molecule can often be described by Mie's
pair potential 3
U(r) = c [(;-) ¹ − (;)],
C
where U(r) is the potential energy between the two atoms, r is the distance between
the two atoms, C, o are positive constants, and > 6 is a constant. The case with
X = 12 is the Lennard- Jones potential and was covered in Lecture #2. For the
purposes of this problem, assume there is a mass 'm' that represents the dynamical
mass of the molecule. In the following, try to simplify the expressions as much as
possible, and consider the frequency whose SI units are Hz.
(a) Find a combination of C, m, o, that has the units of frequency. Does the
combination depend on λ?
(b) Derive the equilibrium position, reg of the system for any >> 6
(c) Derive the frequency of the small oscillations of the system, fosc for any λ > 6.
Simplify the expression until a multiplicative factor of √X-6 appears. Full
credit requires getting this factor because it shows the relevance of having > 6.
Now, you know the role of λ in the formula of the frequency: Sometimes,
dimensional analysis has a limited scope.
(d) Show that the units for the equilibrium position and for the frequency of the
oscillations are consistent based on the units of C, m, o, X.
'
(e) Find the ratio of the equilibrium positions and the frequencies of the small
oscillations between the cases λ = 10 and λ = 14. That is req(λ = 14)/reg(λ =
10), and fosc (X= 14)/ fosc (λ = 10). Hint: the ratio of the equilibrium positions
differs from 1 by about 2%, whereas the the ratio of the two frequencies differs
from 1 by about 54%!
=
Transcribed Image Text:The vibrational properties of a diatomic molecule can often be described by Mie's pair potential 3 U(r) = c [(;-) ¹ − (;)], C where U(r) is the potential energy between the two atoms, r is the distance between the two atoms, C, o are positive constants, and > 6 is a constant. The case with X = 12 is the Lennard- Jones potential and was covered in Lecture #2. For the purposes of this problem, assume there is a mass 'm' that represents the dynamical mass of the molecule. In the following, try to simplify the expressions as much as possible, and consider the frequency whose SI units are Hz. (a) Find a combination of C, m, o, that has the units of frequency. Does the combination depend on λ? (b) Derive the equilibrium position, reg of the system for any >> 6 (c) Derive the frequency of the small oscillations of the system, fosc for any λ > 6. Simplify the expression until a multiplicative factor of √X-6 appears. Full credit requires getting this factor because it shows the relevance of having > 6. Now, you know the role of λ in the formula of the frequency: Sometimes, dimensional analysis has a limited scope. (d) Show that the units for the equilibrium position and for the frequency of the oscillations are consistent based on the units of C, m, o, X. ' (e) Find the ratio of the equilibrium positions and the frequencies of the small oscillations between the cases λ = 10 and λ = 14. That is req(λ = 14)/reg(λ = 10), and fosc (X= 14)/ fosc (λ = 10). Hint: the ratio of the equilibrium positions differs from 1 by about 2%, whereas the the ratio of the two frequencies differs from 1 by about 54%! =
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