Example 1H. The aldol reaction between A and B produces the a-ß unsaturated (tri- substituted) product C. A + BC C₂H₂O CzH14O Given that the para-substituted substrate A can be synthesize from Friedel Craft's acylation; and the IR and HNMR spectrum of B provided below, deduce the structure of A, B and C

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Example 1H. The aldol reaction between A and B produces the a-ß unsaturated (tri-
substituted) product C.
C12H14O
Given that the para-substituted substrate A can be synthesize from Friedel Craft's acylation;
and the IR and ¹HNMR spectrum of B provided below, deduce the structure of A, B and C
IR spectrum of B
Percent Transmission (Transmitance)
3
0.8
0.6
0.4
0.2
¹H NMR spectrum of B
A + B
CgH8O
3000
INFRARED SPECTRUM
2000
Wavenumber (cm-1)
PPM
1000
Provide reasons for your deduction. *Hint: fragment of m/z = 132 observed in abundance for
product C.
Transcribed Image Text:Example 1H. The aldol reaction between A and B produces the a-ß unsaturated (tri- substituted) product C. C12H14O Given that the para-substituted substrate A can be synthesize from Friedel Craft's acylation; and the IR and ¹HNMR spectrum of B provided below, deduce the structure of A, B and C IR spectrum of B Percent Transmission (Transmitance) 3 0.8 0.6 0.4 0.2 ¹H NMR spectrum of B A + B CgH8O 3000 INFRARED SPECTRUM 2000 Wavenumber (cm-1) PPM 1000 Provide reasons for your deduction. *Hint: fragment of m/z = 132 observed in abundance for product C.
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