b. i. Provide mechanisms for the formation of A, B, and C NaOCH₂ CH30H A ii. Which of the products, A, B, or C, reveals that the reaction goes via a carbocation intermediate, and why?
b. i. Provide mechanisms for the formation of A, B, and C NaOCH₂ CH30H A ii. Which of the products, A, B, or C, reveals that the reaction goes via a carbocation intermediate, and why?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Question b:**
i. Provide mechanisms for the formation of A, B, and C
- **Starting Reactant:** A cyclopentane ring with an iodine substituent.
- **Reagents:** `NaOCH3` and `CH3OH` are indicated above the arrow.
- **Products:**
- **Product A:** Cyclopentene with a methoxy group attached.
- **Product B:** Cyclopentene with a double bond.
- **Product C:** A cyclopentane with an isopropyl group.
ii. Which of the products, A, B, or C, reveals that the reaction goes via a carbocation intermediate, and why?
### Explanation:
- **Diagram Explanation:**
- The first drawing shows the starting material—a cyclopentane ring with iodine.
- There is a reaction arrow pointing to the right with `NaOCH3` and `CH3OH` written above it.
- The products are shown sequentially: Product A having a methoxy group, Product B being a cyclopentene, and Product C with an isopropyl group.
- **Concepts:**
- The formation of certain products can indicate the presence of a carbocation intermediate due to rearrangements that stabilize the carbocation. Only one of these products will indicate such a pathway.
In this scenario, analyze the formation of each product to determine which indicates the presence of a carbocation intermediate.
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