Ethers have Lewis basic oxygens, which have the ability 1) to stabilize organometallic reagents 2) to accept hydrogen bonds (but they cannot donate a hydrogen bond due to the lack of heteroatom-H bond) and 3) to solvate cations. 8) Draw the partial charges (8* and 8) for all polar bonds below. 9) Use dotted lines (coordination or hydrogen bonds) to show how the ethers below interact with the following molecules (ions). -Mg-Br CH3 H3C-O O.CH3 The last example exemplifies an ion-dipole interaction. The potassium ion is solvated by the crown ether. This ability allows inorganic salts to be more organic soluble. H3C- H H K+
Ethers have Lewis basic oxygens, which have the ability 1) to stabilize organometallic reagents 2) to accept hydrogen bonds (but they cannot donate a hydrogen bond due to the lack of heteroatom-H bond) and 3) to solvate cations. 8) Draw the partial charges (8* and 8) for all polar bonds below. 9) Use dotted lines (coordination or hydrogen bonds) to show how the ethers below interact with the following molecules (ions). -Mg-Br CH3 H3C-O O.CH3 The last example exemplifies an ion-dipole interaction. The potassium ion is solvated by the crown ether. This ability allows inorganic salts to be more organic soluble. H3C- H H K+
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Ethers have Lewis basic oxygens, which have the ability 1) to stabilize organometallic reagents 2) to accept
hydrogen bonds (but they cannot donate a hydrogen bond due to the lack of heteroatom-H bond) and 3) to
solvate cations.
8) Draw the partial charges (8 and 8-) for all polar bonds below.
9)
Use dotted lines (coordination or hydrogen bonds) to show how the ethers below interact with the
following molecules (ions).
-Mg-Br
H3C
CH 3
LO
H
.0
HỌC .CH3
K+
The last example exemplifies an ion-dipole interaction. The potassium ion is solvated by the crown ether.
This ability allows inorganic salts to be more organic soluble.
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