Electrode equation E' (V) Succinate + CO2 + 2 H+ + 2 e¯ = a-ketoglutarate + H₂O -0.670 Acetate + 2 H+ + 2 e¯ = acetaldehyde -0.580 2 H+ + 2e H₂ -0.421 a-Ketoglutarate + CO2 + 2 H+ + 2e isocitrate -0.380 Cystine + 2 H+ + 2 e¯ = 2 cysteine -0.340 NAD+ + 2 H+ + 2 e˜¯ = NADH + H+ -0.320 NADP+ + 2 H+ + 2 e¯ = NADPH + H+ -0.324 Acetaldehyde + 2 H+ + 2e ethanol -0.197 Pyruvate +2 H+ + 2 e¯ = lactate -0.185 Oxaloacetate + 2 H+ + 2e malate -0.166 FAD + 2 H+ + 2 e¯ = FADH₂ (in flavoproteins) +0.031 Fumarate 2 H+ + 2 e¯ succinate +0.031 Ubiquinone +2 H+ + 2 e¯ ubiquinol +0.045 2 cytochrome b (ox) + 2 e¯ = 2 cytochrome b(red) 2 cytochrome c (ox) + 2 e 2 cytochrome ((red) +0.070 +0.254 2 cytochrome a3 (ox) + 2 ¯ = 2 cytochrome a3(red) +0.385 O2 + 2H + 2 e¯¯ = H₂O +0.816
Electrode equation E' (V) Succinate + CO2 + 2 H+ + 2 e¯ = a-ketoglutarate + H₂O -0.670 Acetate + 2 H+ + 2 e¯ = acetaldehyde -0.580 2 H+ + 2e H₂ -0.421 a-Ketoglutarate + CO2 + 2 H+ + 2e isocitrate -0.380 Cystine + 2 H+ + 2 e¯ = 2 cysteine -0.340 NAD+ + 2 H+ + 2 e˜¯ = NADH + H+ -0.320 NADP+ + 2 H+ + 2 e¯ = NADPH + H+ -0.324 Acetaldehyde + 2 H+ + 2e ethanol -0.197 Pyruvate +2 H+ + 2 e¯ = lactate -0.185 Oxaloacetate + 2 H+ + 2e malate -0.166 FAD + 2 H+ + 2 e¯ = FADH₂ (in flavoproteins) +0.031 Fumarate 2 H+ + 2 e¯ succinate +0.031 Ubiquinone +2 H+ + 2 e¯ ubiquinol +0.045 2 cytochrome b (ox) + 2 e¯ = 2 cytochrome b(red) 2 cytochrome c (ox) + 2 e 2 cytochrome ((red) +0.070 +0.254 2 cytochrome a3 (ox) + 2 ¯ = 2 cytochrome a3(red) +0.385 O2 + 2H + 2 e¯¯ = H₂O +0.816
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:Electrode equation
E' (V)
Succinate + CO2 + 2 H+ + 2 e¯ =
a-ketoglutarate + H₂O
-0.670
Acetate + 2 H+ + 2 e¯ = acetaldehyde
-0.580
2 H+ + 2e
H₂
-0.421
a-Ketoglutarate + CO2 + 2 H+ + 2e isocitrate
-0.380
Cystine + 2 H+ + 2 e¯ = 2 cysteine
-0.340
NAD+ + 2 H+ + 2 e˜¯ = NADH + H+
-0.320
NADP+ + 2 H+ + 2 e¯ = NADPH + H+
-0.324
Acetaldehyde + 2 H+ + 2e
ethanol
-0.197
Pyruvate +2 H+ + 2 e¯ = lactate
-0.185
Oxaloacetate + 2 H+ + 2e malate
-0.166
FAD + 2 H+ + 2 e¯ = FADH₂ (in flavoproteins)
+0.031
Fumarate 2 H+ + 2 e¯ succinate
+0.031
Ubiquinone +2 H+ + 2 e¯
ubiquinol
+0.045
2 cytochrome b (ox) + 2 e¯ = 2 cytochrome b(red)
2 cytochrome c (ox) + 2 e 2 cytochrome ((red)
+0.070
+0.254
2 cytochrome a3 (ox) + 2 ¯ = 2 cytochrome a3(red)
+0.385
O2 + 2H + 2 e¯¯ = H₂O
+0.816
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