egg< > :4) Provide a detailed mechanism for the dehydration of 3-methyl-2-butanol withaqueous sulfuric acid and heat. Use arrows to show movements of electrons.5) Draw the mechanisms for the following products:H.SO, (concd)☐OH120 °COHconc. H₂SOOHconc. H₂SO818Healed 4) Provide a detailed mechanism for theVis

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Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 64AP: The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold...

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(b) 1,2-hexanediol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. / / ? ChemDoodleⓇ Which process does this employ? 1. Hg(OAc)2, H₂O; 2. NaBH4 1. BH3; 2. H₂O2, NaOH 0804, H₂O2 Sn [F
The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?
Be sure to answer all parts. Synthesize the following compound from cyclohexanol using any other organic or inorganic compounds. CHO Part 1 out of 2 Grignard reaction: OH OH [1] X draw structure .. Draw the intermediate product formed and select the correct reagent W. O H;SO, O Cro3, H,SO. H,0 O MCPBA O Og Select the correct reagent X. O CH, O CHẠI O CH,OH O CH,MGB. 3 amenupts left Check my work Next part
5. Draw the products of the following reactions: HBr ether Lindlar catalyst NAOH H2O, heat ...Br H2O H;0 heat CN OH PBrs H3C CH3 ether ČH3 H3C CH, CH3CH2CH2OH water H3C Li CH;CH2 -C=C-CH3 NH3
ll mobily ? 4:13 PM O 21% O < Homework - carboxylic a... CH3CHCH2CH2CHCH3 CH3CCO2H CH3 (c) .CO2H (d) CH3 CH3CCN CH3 (g) Br (h) CN BRCH2CHCH2CH2CO2H Q2: Draw structures corresponding to the following IUPAC names: (a) cis-1,2-Cyclohexanedicarboxylic acid (b) Heptanedioic acid (c) 2-Hexen-4-ynoic acid (d) 4-Ethyl-2-propyloctanoic acid (e) 2-Cyclobutenecarbonitrile Q3: How could you convert butanoic acid into the following compounds? Write each step showing the reagents needed. (a) 1-Butanol (b) 1-Bromobutane (c) 1-Butene How could you convert each of the following compounds into butanoic acid? Write each step showing all reagents. (a) 1-Butanol (b) 1-Bromobutane (c) 1-Butene How could you convert butanenitrile into the following compounds? Write each step showing the reagents needed. (a) 1-Butanol (b) Butylamine
(a) 2-methyl-2-pentanol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. AAVIL ? ChemDoodleⓇ Which process does this employ? 1. Hg(OAc)2, H₂O; 2. NaBH4 01. BH3; 2. H₂O2, NaOH OsO4, H₂O2 On n [ ]#
Which set of reagents would be appropriate to synthesize bromobenzene from benzene? O 1. HNO3 in H2SO4; 2. H2CrO4 and heat O 1. H2CrO4 and heat; 2. H2 Pd/C O Br2 and FeBr3 O 1. CH3CH2CHCI and AICI3; 2. H2CRO4 and heat O4B12 and Fe O Heat and Br2 OBR2, HCI
Answet with the correct product for each reaction:
What is the purpose of a slyl ether? O To prevent the formution df carbonic acids To protect ketones from orgnometalic reagerts and uther magents O To protect esters from organometalic reaperts and otbe rapts O To protect alkcohols from orpinometalic ragerts and other prts
None
5. Draw the mechanism arrows for each of the reactions below. (8pts) NaNH2 a. b. C. CI .Cl I NaCN Base Catalyzed Keto-Enol Tautomerization H3O+ HO H₂N CI CN CN H
Draw the products below

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