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(e) (p) ()) "HIVIT MgBr (q) (e) 9SH nucleophiles in a-e. Problem 17.25: Draw the major product for the reaction between cyclohex-2-en-1-one and each of the

(e) (p) ()) "HIVIT MgBr (q) (e) 9SH nucleophiles in a-e. Problem 17.25: Draw the major product for the reaction between cyclohex-2-en-1-one and each of the

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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CH3 Problem 17.25: Draw the major product for the reaction between cyclohex-2-en-1-one and each of the nucleophiles in a-e. (a) LIAIHA (e) MgBr (e) (p) ())
Transcribed Image Text:CH3 Problem 17.25: Draw the major product for the reaction between cyclohex-2-en-1-one and each of the nucleophiles in a-e. (a) LIAIHA (e) MgBr (e) (p) ())
Expert Solution
Step 1 Nucleophile attack in Organic reaction

a) CH3SNa Methanethiol , generate a soft nucleophile ,center at sulfur atom.

Soft nucleophile will attack on Soft electrophillic center i.e. on Alkene Carbon

b) This is an Example of Witting Reaction,  Alkene will Form by replacing carbonyl center 

c) This is an example of Cross Aldol Reaction. Nucleophile will attack on carbonyl center

d) Grignard reagent, a hard nucleophile , attack on carbonyl center of reactant

e) LiALH4 a reducing agent, used for reduction of carbonyls.

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