camparing vanious alkyl halides reactivity toward SN1 reactions using water as a nucleopnile Entry # Alko| halide K(x101min") 0.2231 t 0.0041 Eq(kcsI) COHS CH 2 C1 Cetts CH2Br coHs CHCI 2 Ce Hs CHCIBr Cuts CCI3 CoHs CC12 Br A 212214) 21.2 2. 5684I 0.085 19.1 2.214 E 0.037 23.3 31.08 1 0.19 110.5 0.9 4 21.9 20.5 19.2 reaction was dame in 50%. aqueOUS acetune at 30°C reaction n scherre fur entry #1 H2O -> acetane a) which is a better leaving group, wby? b) unat isthe structure of the intermediale of the reaction in entry #3 c) Does the presence ofa secund halogen Increase or decrcase the stability ot carbocation.

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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camparing vanious alkyl halides
reactivity toward SN1 reactions using
water as a nucleopnile
Entry # Alko| halide K(x101min")
0.2231 t 0.0041
Eq(kcsI)
COHS CH 2 C1
Cetts CH2Br
coHs CHCI 2
Ce Hs CHCIBr
Cuts CCI3
CoHs CC12 Br A 212214)
21.2
2.
5684I 0.085
19.1
2.214 E 0.037
23.3
31.08 1 0.19
110.5 0.9
4
21.9
20.5
19.2
reaction was dame in 50%. aqueOUS
acetune at 30°C
reaction
n scherre
fur entry #1
H2O
->
acetane
Transcribed Image Text:camparing vanious alkyl halides reactivity toward SN1 reactions using water as a nucleopnile Entry # Alko| halide K(x101min") 0.2231 t 0.0041 Eq(kcsI) COHS CH 2 C1 Cetts CH2Br coHs CHCI 2 Ce Hs CHCIBr Cuts CCI3 CoHs CC12 Br A 212214) 21.2 2. 5684I 0.085 19.1 2.214 E 0.037 23.3 31.08 1 0.19 110.5 0.9 4 21.9 20.5 19.2 reaction was dame in 50%. aqueOUS acetune at 30°C reaction n scherre fur entry #1 H2O -> acetane
a) which is a better leaving group, wby?
b) unat isthe structure of the intermediale
of the reaction in entry #3
c) Does the presence ofa secund halogen
Increase or decrcase the stability ot
carbocation.
Transcribed Image Text:a) which is a better leaving group, wby? b) unat isthe structure of the intermediale of the reaction in entry #3 c) Does the presence ofa secund halogen Increase or decrcase the stability ot carbocation.
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