Dye (1D Box) Oxacarbocyanine (C3) Oxadicarbocyanine (C5) Oxatricarbocyanine (C7) Thiacarbocyanine (C3) Code 0-3 0-5 0-7 S-3 C 100 Structure Et Et genyo D > (nm) Number of Experimental -electrons 485 582 686 nm 560 nm 10 11 8 n_HOMO G n_LUMO Guess Observe Colour of Solutio orange vilote blue Vilote
Dye (1D Box) Oxacarbocyanine (C3) Oxadicarbocyanine (C5) Oxatricarbocyanine (C7) Thiacarbocyanine (C3) Code 0-3 0-5 0-7 S-3 C 100 Structure Et Et genyo D > (nm) Number of Experimental -electrons 485 582 686 nm 560 nm 10 11 8 n_HOMO G n_LUMO Guess Observe Colour of Solutio orange vilote blue Vilote
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Dye (1D Box)
Oxacarbocyanine (C3)
Oxadicarbocyanine (C5)
Oxatricarbocyanine (C7)
Thiacarbocyanine (C3)
Thiacarbocyanine (C5)
Thiacarbocyanine (C7)
1,4-diphenyl-1,3-butadiene
1,6-diphenyl-1,3,5-hexatriene
Dye (2D Box)
benzene
Lx 0.42 nm and Ly= 0.42 nm)
naphthalene
(Lx = 0.64 nm and Ly = 0.42 nm)
anthracene
Lx 0.87 nm and Ly= 0.42 nm)
Code
porphyrin
[Lx = 1.0 nm and Ly= 1.0 nm)
0-3
0-5
0-7
S-3
1,8-diphenyl-1,3,5,7-octatetraene DPO
S-5
S-7
DPB
DPH
Structure
O
Et
Et
guyx
anado
> (nm)
Experimental
485
582
686 nm
560 nm
656 nm
760.99nm
255
286
375
400
Number of
-electrons
6
12
18
26
8
10
11
8
10
12
n_HOMO
n_X_HOMO-
n_y_HOMO
G
n_LUMO
n_X_LUMO-
n_y_LUMO
Guess Observed
Colour of Solution
orange
vilote
blue
Vilote
blue
green
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