Dye (1D Box)Oxacarbocyanine (C3)Oxadicarbocyanine (C5)Oxatricarbocyanine (C7)Thiacarbocyanine (C3)Thiacarbocyanine (C5)Thiacarbocyanine (C7)1,4-diphenyl-1,3-butadiene1,6-diphenyl-1,3,5-hexatrieneDye (2D Box)benzeneLx 0.42 nm and Ly= 0.42 nm)naphthalene(Lx = 0.64 nm and Ly = 0.42 nm)anthraceneLx 0.87 nm and Ly= 0.42 nm)Codeporphyrin[Lx = 1.0 nm and Ly= 1.0 nm)0-30-50-7S-31,8-diphenyl-1,3,5,7-octatetraene DPOS-5S-7DPBDPHStructureOEtEtguyxanado> (nm)Experimental485582686 nm560 nm656 nm760.99nm255286375400Number of-electrons61218268101181012n_HOMOn_X_HOMO-n_y_HOMOGn_LUMOn_X_LUMO-n_y_LUMOGuess ObservedColour of SolutionorangeviloteblueVilotebluegreen

Since you have asked a multiple sub-part question, we will solve the first three sub-parts for you.…

Dye (1D Box) Oxacarbocyanine (C3) Oxadicarbocyanine (C5) Oxatricarbocyanine (C7) Thiacarbocyanine (C3) Code 0-3 0-5 0-7 S-3 C 100 Structure Et Et genyo D > (nm) Number of Experimental -electrons 485 582 686 nm 560 nm 10 11 8 n_HOMO G n_LUMO Guess Observe Colour of Solutio orange vilote blue Vilote

Dye (1D Box) Oxacarbocyanine (C3) Oxadicarbocyanine (C5) Oxatricarbocyanine (C7) Thiacarbocyanine (C3) Code 0-3 0-5 0-7 S-3 C 100 Structure Et Et genyo D > (nm) Number of Experimental -electrons 485 582 686 nm 560 nm 10 11 8 n_HOMO G n_LUMO Guess Observe Colour of Solutio orange vilote blue Vilote

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Techniques and applications of quantum theory

Quantum theory, often known as quantum physics, is the foundation of modern physics and encompasses the nature and behavior of matter and energy at the atomic and molecular levels. As the exact nature and behavior of atomic and subatomic particles are impossible to determine, the laws of classical physics do not apply to this discipline. As a result, quantum field theory is primarily based on assumptions and probabilities.

Question

Dye (1D Box)
Oxacarbocyanine (C3)
Oxadicarbocyanine (C5)
Oxatricarbocyanine (C7)
Thiacarbocyanine (C3)
Thiacarbocyanine (C5)
Thiacarbocyanine (C7)
1,4-diphenyl-1,3-butadiene
1,6-diphenyl-1,3,5-hexatriene
Dye (2D Box)
benzene
Lx 0.42 nm and Ly= 0.42 nm)
naphthalene
(Lx = 0.64 nm and Ly = 0.42 nm)
anthracene
Lx 0.87 nm and Ly= 0.42 nm)
Code
porphyrin
[Lx = 1.0 nm and Ly= 1.0 nm)
0-3
0-5
0-7
S-3
1,8-diphenyl-1,3,5,7-octatetraene DPO
S-5
S-7
DPB
DPH
Structure
O
Et
Et
guyx
anado
> (nm)
Experimental
485
582
686 nm
560 nm
656 nm
760.99nm
255
286
375
400
Number of
-electrons
6
12
18
26
8
10
11
8
10
12
n_HOMO
n_X_HOMO-
n_y_HOMO
G
n_LUMO
n_X_LUMO-
n_y_LUMO
Guess Observed
Colour of Solution
orange
vilote
blue
Vilote
blue
green

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