Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Title: Hydrogenation of Alkynes Using Lindlar Catalyst**
**Description:**
**Reaction Overview:**
The chemical reaction involves the partial hydrogenation of an alkyne to an alkene using a Lindlar catalyst. The unsaturated starting compound is a long-chain ester with the following structure:
- **Structure**: HOCH₂-C≡C-(CH₂)₇-C(O)OCH₃
- **Reagent**: H₂ (Hydrogen gas)
- **Catalyst**: Lindlar catalyst
**Explanation:**
The molecule consists of an alkyne group (a triple bond between carbons), which is a linear structure. The Lindlar catalyst, which is a palladium catalyst poisoned with lead salts, facilitates the selective hydrogenation of the triple bond to a cis-alkene without further reduction to an alkane. This is essential for forming alkenes with specific geometric configurations.
**Product of the Reaction:**
Upon reaction with hydrogen in the presence of Lindlar catalyst, the alkyne group (-C≡C-) is converted to a cis-alkene (C=C) while maintaining the rest of the molecular structure intact. The expected product will maintain the ester functionality and other groups present in the starting material.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F13f99433-34aa-4e92-8117-34b0d2272faf%2F5c1ae1b8-bdbf-4b10-95b7-a2b45c0d45e4%2F8r1b9xb_processed.png&w=3840&q=75)
Transcribed Image Text:**Title: Hydrogenation of Alkynes Using Lindlar Catalyst**
**Description:**
**Reaction Overview:**
The chemical reaction involves the partial hydrogenation of an alkyne to an alkene using a Lindlar catalyst. The unsaturated starting compound is a long-chain ester with the following structure:
- **Structure**: HOCH₂-C≡C-(CH₂)₇-C(O)OCH₃
- **Reagent**: H₂ (Hydrogen gas)
- **Catalyst**: Lindlar catalyst
**Explanation:**
The molecule consists of an alkyne group (a triple bond between carbons), which is a linear structure. The Lindlar catalyst, which is a palladium catalyst poisoned with lead salts, facilitates the selective hydrogenation of the triple bond to a cis-alkene without further reduction to an alkane. This is essential for forming alkenes with specific geometric configurations.
**Product of the Reaction:**
Upon reaction with hydrogen in the presence of Lindlar catalyst, the alkyne group (-C≡C-) is converted to a cis-alkene (C=C) while maintaining the rest of the molecular structure intact. The expected product will maintain the ester functionality and other groups present in the starting material.
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