Draw the possible products of this epoxide ring-opening reaction. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicableIgnore any inorganic byproducts. 1) NaOH / H2O 2) dilute HCI Q
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- Draw the products resulting from addition of a Grignard reagent to an aldehyde. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicableIgnore any inorganic byproducts. 1) PhMgCl (C6H5MgCl) 2) HCI / H₂ODraw the possible products of this epoxide ring-opening reaction. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicableIgnore any inorganic byproducts. 411 1) NaOH/H₂O 2) dilute HCIDraw the products of this reduction of a ketone with sodium borohydride. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicableIgnore any inorganic byproducts.
- a) Draw the mechanism, using good curved arrow notation, for the reaction of 2-methyl-2- butene with bromine in water, omitting any stereochemistry: b) (R)-3-butyn-2-ol is treated with 2 mol of HBr, yielding optically active Compound A (C4H8OBr2). Draw the structure of the reaction with the correct stereochemistry. c) Name Compound A above, including stereochemistry. d) Compound A is treated with HBr to yield Compound B (C4H7Br3). The resulting solution is optically inactive. Draw the product(s) obtained and explain why there is a loss in optical activity.:&:$:$;$$;$&:&Draw the possible products of this epoxide ring-opening reaction. Use a dash or wedge to indicate the stereochemistry of substituents on asymmetric centers, where applicable. Ignore any inorganic byproducts.
- Consider the mechanism for the reaction of cyclohexene and bromine at -5 °C in CCI,. The bromines in the equation are numbered to differentiate them in the mechanistic steps. 0. Identify the curved arrows needed for the mechanism, then draw the key intermediate and product. Clearly show stereochemistry, by drawing a wedge and dash bond at each chirality center (including hydrogen atoms). Draw one enantiomer for any racemates. CCI -5°C +Br,-Br₂ dibromocyclohexane A. Select the curved arrow(s) needed for step 1. A curved arrow starts from the lone pair of bromine 1 and points to an alkene carbon. Two curved arrows start on bromine 1, each pointing to an alkene carbon. A curved arrow starts from the alkene x bond and points to bromine 1. A curved arrow starts from the Br-Br bond and points to bromine 2. B. Draw 1 organic species and 1 inorganic species formed in step 1. Include charges and non-bonding electrons. Select Draw Rings More /Y C H Br EraseAlkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two O Hint in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. The first step of the reaction, hydroboration, involves addition of BH, to the double bond, with -BH, attached to one carbon and hydrogen Be sure to draw hydrogens on oxygen, where applicable. attached to the other. Consider both Rings the regioselectivity and the Select Draw More Erase stereochemistry of this addition. H Diborane, B,H,, is a source of borane, BH,, and can be used 1. B2H6, interchangeably. Diglyme is a solvent. diglyme 2. H2О2, НО", The product or products of the reaction are characterized as being O S. O racemic. O achiral. O R,S (and/or S,R). O R. O S,S. O R.R. O diastereomers.Draw the major organic product(s) for the following reactions, including stereochemistry when appropriate