Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Draw the major product of this reaction. Ignore inorganic byproducts. CI O Q

Draw the major product of this reaction. Ignore inorganic byproducts. CI O Q

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

# 19 help

**Reaction Problem:** **Task:** Draw the major product of this reaction. Ignore inorganic byproducts. **Given Structure:** - **Reactant:** An acyl chloride compound. The structure contains a carbonyl group (C=O) with a chlorine (Cl) atom attached to the carbonyl carbon. **Reagents:** 1. **(CH₃)₂CuLi (excess):** This reagent is a Gilman reagent, commonly used for nucleophilic substitution reactions. 2. **H₂O:** Water is used in the second step to quench the reaction. **Instructions for Drawing the Product:** - The arrow indicates that the reaction proceeds from the acyl chloride reactant to the final product, which needs to be drawn in the space provided (dashed box labeled "Drawing"). **Explanation of Reaction Mechanism:** - The Gilman reagent, in excess, will replace the chlorine atom with a methyl group (–CH₃), resulting in a ketone as the major product. - This is a typical conversion of an acyl chloride to a ketone using an organocuprate reagent. By utilizing these reagents, the transformation focuses on replacing the leaving group (Cl) while stabilizing the carbonyl center, ultimately forming a more stable compound (ketone) with a methyl substituent.
Transcribed Image Text:**Reaction Problem:** **Task:** Draw the major product of this reaction. Ignore inorganic byproducts. **Given Structure:** - **Reactant:** An acyl chloride compound. The structure contains a carbonyl group (C=O) with a chlorine (Cl) atom attached to the carbonyl carbon. **Reagents:** 1. **(CH₃)₂CuLi (excess):** This reagent is a Gilman reagent, commonly used for nucleophilic substitution reactions. 2. **H₂O:** Water is used in the second step to quench the reaction. **Instructions for Drawing the Product:** - The arrow indicates that the reaction proceeds from the acyl chloride reactant to the final product, which needs to be drawn in the space provided (dashed box labeled "Drawing"). **Explanation of Reaction Mechanism:** - The Gilman reagent, in excess, will replace the chlorine atom with a methyl group (–CH₃), resulting in a ketone as the major product. - This is a typical conversion of an acyl chloride to a ketone using an organocuprate reagent. By utilizing these reagents, the transformation focuses on replacing the leaving group (Cl) while stabilizing the carbonyl center, ultimately forming a more stable compound (ketone) with a methyl substituent.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 3 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Carboxylic Acids and their Derivatives
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS