Draw the line angle formulas for all products obtained when the following compound is subjected to ozonolysis using excess ozone with reductive work-up.
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- Outine the synthetic sequence for preparing the following product from benzene. a) COOH b)Give the reagents suitable for effecting each of the following reactions, and write the principal products. If an ortho, para mixture is expected, show both. If the meta isomer is the expected major product, wrote only that isomer. Nitration of benzene Nitration of the product of (a) Bromination of toluene Bromination of (trifluoromethyl)benzene Sulfonation of anisole Sulfonation of acetanilide (C6H5NHCOCH3) Chlorination of bromobenzene Friedel-Crafts alkylation of anisole with benzyl chloride Friedel-Crafts acylation of benzene with benzoyl chloride Nitration of the product of (i) Clemmensen reduction of product from (i) Wolff-Kishner reduction of product from (i)Question (a) Discuss why the reactivity of nitration towards benzene increases when a mixture concentrated nitric acid (HNO:) mixed with sulphuric acid (H2SO4). You may explain it from the aspect of electrophile formed in the reaction between HNO3 and H2SO4.
- Substitutions on aromatic rings are generally carried out by electrophilic substitution, but for the synthesis of phenolic compounds and alkoxy benzene it is carried out by nucleophilic substitution, explain why this is so .Give an example of reaction that supports the unusual stability of benzene versus alkenes. You need to provide the products, where applicable.Please answer the following: Cyclopropyl chloride can be prepared by the radical chlorination of cyclopropane, Write an overall equation for the reaction Suggest suitable reaction condition Write a stepwise mechanism for the radical halogenation reaction.
- When bromomethane undergoes solvolysis in a solvent mixture composed of 90% water/10% acetone, the reaction rate is faster than when the same compound is solvolyzed in 80% water/20% acetone. Explain.Heterocyclic compounds are present in naturally occurring substances and their syntheticcompounds are produced for various industrial applications. Furan is one such heterocycliccompound which is more reactive than benzene towards electrophilic aromatic substitutionreaction.1.Analyze the different substitution products formed in case of furan when it is reacted withiodine. Write the reaction mechanism involved when furan reacted with iodine andevaluate the formation of products.What is the background on the chemistry of electrophilic aromatic substitution reactions, what is the importance of nitration reactions in organic synthesis, and the reactivity of methyl benzoate, a methyl ester of benzoic acid. With references
- Can someone Outline a chemical reaction for the formation of the compound and explain it and detail I really need to understand what is going on in the mechanismGive clear detailed Solution with explanation neededName and Draw the structures of all possible chemical (Electrophilic aromatic substitution) reactions of the Phenolcompound namely; Halogenation (Chlorination or Bromination)