Draw the four possible aldol addition products for the reaction between these two carbonyl compounds. Use the indicated prompts in each box below to submit the products. Ignore inorganic byproducts. Select to 1. NaOH Draw (Enolate A + + Aldehyde A) Select to Draw (Enolate B + Aldehyde A) + Aldehyde A Aldehyde B થ 2. Neutralizing work-up Draw (Enolate A+ Aldehyde B) Select to Draw (Enolate B+ ! Aldehyde B)

Draw the four possible aldol addition products for the reaction between these two carbonyl compounds. Use the indicated prompts in each box below to submit the products. Ignore inorganic byproducts. Select to 1. NaOH Draw (Enolate A + + Aldehyde A) Select to Draw (Enolate B + Aldehyde A) + Aldehyde A Aldehyde B થ 2. Neutralizing work-up Draw (Enolate A+ Aldehyde B) Select to Draw (Enolate B+ ! Aldehyde B)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Draw the four possible aldol addition products for the reaction between these two carbonyl compounds. Use the indicated prompts in each box below to submit the products. Ignore inorganic byproducts. 10: Aldehyde A H FO Aldehyde B H 0 1. NaOH 2. Neutralizing work- up
Draw the aldol product formed from each pair of starting materials using −OH, H2O.
The least reactive carboxylic acid derivative is carboxylate itself. In biological systems, the carboxylate can be activated by converting into an acyl phosphate ester. Draw the major organic product of the phosphate ester with each of the given reagents.
The enolate of an ester can be treated with a ketone to give a beta-hydroxy ester. Draw a mechanism for this aldol-like reaction. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph. EtO 1) LDA 2) ΕΙΟ OH श्र Step 1 * Incorrect. Which of the mechanistic steps is shown in this step of the mechanism? Draw step 1 of the mechanism. HC CH CH3 CH3 Edit Drawing CH3
7. When the following ketone is treated with sodium hydroxide, two different enolates can form. a. Draw the two enolates, including an arrow pushing mechanism for their formation and any relevant resonance structures. NaOH b. Which enolate is favored when using sodium hydroxide as the base? Explain. c. Predict the product of the reaction and include an arrow-pushing mechanism. 1. NaOH 2. Br
Draw the major organic product that forms in an intramolecular aldol condensation. Remember that heat is applied.
See image below
2‑Phenylacetaldehyde with benzaldehyde in the presence of sodium hydroxide undergoes a crossed aldol reaction.
indicate which component will act as the enolate in the reaction
Select to Draw (Enolate A + Aldehyde A) Select to Draw (Enolate B+ Aldehyde A) 1. NaOH I H Aldehyde A Aldehyde B + O= + H 2. Neutralizing work-up I Draw (Enolate A + Aldehyde B) Select to Draw (Enolate B + Aldehyde B) I I I I I I I I I I I
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