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Ketones, Aldehydes and Epoxides: Assume "then H,0" is included if a protonation step is needed R K V Acid Chlorides: Assume AICI, or pyridine is present if needed w Y YY Other Reagents: 1 H3O* (dilute H,SO,) or H3O*, heat 2 conc. H,SO4, heat 11 PCC in CH,Cl2 12 Na,Cr2O7, H2SO,, H2O 13 BH3 THF or 9-BBN, then H2O2, NAOH 14 Hg(OAc)2, H2O, then NaBH, 15 O3, then Zn, HCI or DMS 16 MCPBA or CH3CO3H 17 Brz, light or NBS, heat 18 HBr 19 HBr, ROOR 21 Brz, FeBr3 22 Mg. Et,0 23 Cl2, AICI3 24 SOCI2, pyridine 25 HNO3, H2SO4 26 fuming H2SO4 27 Fe, HCI; then NaOH 3 NaOEt 4 t-BUOK 5 H2, Pt 6 H2, Lindlar's catalyst 7 Na, NH3 8 LAH or xs LAH, then H20 9 NABH4, CH,OH 10 NABH;CN, pH 5 28 Zn(Hg), HCI 29 KCN, or KCN + HCN 20 PBr3 30 CO2, then H3O* 31 (H'). HO (-H2O) Grignard, Wittig and Gilman Reagents: Assume "then H,0" is included if a protonation step is needed 32 NH3 (1 or 2 equiv.) 33 CH;NH2 (1 or 2 equiv) 34 (CH3)2NH (1 or 2 equiv) 35 EINH2 (1 or 2 equiv) 36 PHCH,NH2 (1 or 2 equiv). 37 LDA, -78 °C MgBr MeMgBr EIMgBr PhMgBr G1 G2 G3 G4 CuLi Me,CuLi Et,Culi (PHCH2),CuLi 38 NaH, 25 °C 39 LIAI(OR),H, then H20 40 DIBAH, then H2O 41 Brz. [H3O*] 42 Brz, NaOH 43 Pyridine G5 G6 G7 G8 MePh,P=CH2 PhyP=CHCH, PhyP=CHCO,Et PhyP=CHP. W1 w2 W3 W4

Ketones, Aldehydes and Epoxides: Assume "then H,0" is included if a protonation step is needed R K V Acid Chlorides: Assume AICI, or pyridine is present if needed w Y YY Other Reagents: 1 H3O* (dilute H,SO,) or H3O*, heat 2 conc. H,SO4, heat 11 PCC in CH,Cl2 12 Na,Cr2O7, H2SO,, H2O 13 BH3 THF or 9-BBN, then H2O2, NAOH 14 Hg(OAc)2, H2O, then NaBH, 15 O3, then Zn, HCI or DMS 16 MCPBA or CH3CO3H 17 Brz, light or NBS, heat 18 HBr 19 HBr, ROOR 21 Brz, FeBr3 22 Mg. Et,0 23 Cl2, AICI3 24 SOCI2, pyridine 25 HNO3, H2SO4 26 fuming H2SO4 27 Fe, HCI; then NaOH 3 NaOEt 4 t-BUOK 5 H2, Pt 6 H2, Lindlar's catalyst 7 Na, NH3 8 LAH or xs LAH, then H20 9 NABH4, CH,OH 10 NABH;CN, pH 5 28 Zn(Hg), HCI 29 KCN, or KCN + HCN 20 PBr3 30 CO2, then H3O* 31 (H'). HO (-H2O) Grignard, Wittig and Gilman Reagents: Assume "then H,0" is included if a protonation step is needed 32 NH3 (1 or 2 equiv.) 33 CH;NH2 (1 or 2 equiv) 34 (CH3)2NH (1 or 2 equiv) 35 EINH2 (1 or 2 equiv) 36 PHCH,NH2 (1 or 2 equiv). 37 LDA, -78 °C MgBr MeMgBr EIMgBr PhMgBr G1 G2 G3 G4 CuLi Me,CuLi Et,Culi (PHCH2),CuLi 38 NaH, 25 °C 39 LIAI(OR),H, then H20 40 DIBAH, then H2O 41 Brz. [H3O*] 42 Brz, NaOH 43 Pyridine G5 G6 G7 G8 MePh,P=CH2 PhyP=CHCH, PhyP=CHCO,Et PhyP=CHP. W1 w2 W3 W4

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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indicate which component will act as the enolate in the reaction
Alkyl Halides (X = CI, Br or I): Assume AICI, is present if needed 2 of 2 G un acid catalyst [H+], or pyridine, is present if needed. он OH OH CHJOH AA BB DD EE FF GG HH Ketones, Aldehydes and Epoxides: Assume "then H,0" is included if a protonation step is needed K. P R V Acid Chlorides: Assume AICI, or pyridine is present if needed YY zZ Other Reagents: 11 PCC in CH2C2 21 Br2, FeBr3 22 Mg. Et,0 23 Cl2, AICI3 24 SOCI2, pyridine 25 HNO3, H2SO4 26 fuming H2SO4 1 H3O* (dilute H2SO4) or H3O*, heat 2 conc. H2SO4, heat 3 NaOEt 12 NazCr207, H2S04, H2O 13 BH3•THF or 9-BBN, then H2O2, NaOH 14 Hg(OAc)2, H2O, then NaBH4 15 O3, then Zn, HCI or DMS 16 MCPBA or CH;CO3H 17 Br2, light or NBS, heat 4 t-BUOK 5 H2, Pt 6 H2, Lindlar's catalyst 7 Na, NH3 8 LAH or xs LAH, then H20 9 NABH4, CH3OH 10 NABH,CN, pH 5 27 Fe, HCI; then NaOH 28 Zn(Hg). НCI 29 KCN, or KCN + HCN 30 CO2, then H30* 18 HBr 19 HBr, ROOR 20 PB13 31 (H*]. HOʻ 32 NH3 (1 or 2 equiv.) 33 CH,NH2 (1 or 2 equiv) 34 (CH3)½NH (1 or 2 equiv) 35 EINH2 (1 or 2 equiv) 36 PHCH,NH2 (1 or 2 equiv). 37 LDA, -78 °C (-H20) Grignard, Wittig and Gilman Reagents: Assume "then H,0" is included if a protonation step is needed MgBr MeMgBr EtMgBr PhMgBr G1 G2 G3 G4 CuLi Me,Culi Et,Culi (PHCH2),CULI 38 NaH, 25 °C 39 LIAI(OR);H, then H20 40 DIBAH, then H2O 41 Br2. [H3O*] 42 Br2, NaOH 43 Pyridine G5 G6 G7 G8 MePh,P=CH2 PhyP=CHCH3 PhyP=CHCO,Et PhyP=CHPH W1 w2 W3 W4
Transcribed Image Text:Alkyl Halides (X = CI, Br or I): Assume AICI, is present if needed 2 of 2 G un acid catalyst [H+], or pyridine, is present if needed. он OH OH CHJOH AA BB DD EE FF GG HH Ketones, Aldehydes and Epoxides: Assume "then H,0" is included if a protonation step is needed K. P R V Acid Chlorides: Assume AICI, or pyridine is present if needed YY zZ Other Reagents: 11 PCC in CH2C2 21 Br2, FeBr3 22 Mg. Et,0 23 Cl2, AICI3 24 SOCI2, pyridine 25 HNO3, H2SO4 26 fuming H2SO4 1 H3O* (dilute H2SO4) or H3O*, heat 2 conc. H2SO4, heat 3 NaOEt 12 NazCr207, H2S04, H2O 13 BH3•THF or 9-BBN, then H2O2, NaOH 14 Hg(OAc)2, H2O, then NaBH4 15 O3, then Zn, HCI or DMS 16 MCPBA or CH;CO3H 17 Br2, light or NBS, heat 4 t-BUOK 5 H2, Pt 6 H2, Lindlar's catalyst 7 Na, NH3 8 LAH or xs LAH, then H20 9 NABH4, CH3OH 10 NABH,CN, pH 5 27 Fe, HCI; then NaOH 28 Zn(Hg). НCI 29 KCN, or KCN + HCN 30 CO2, then H30* 18 HBr 19 HBr, ROOR 20 PB13 31 (H*]. HOʻ 32 NH3 (1 or 2 equiv.) 33 CH,NH2 (1 or 2 equiv) 34 (CH3)½NH (1 or 2 equiv) 35 EINH2 (1 or 2 equiv) 36 PHCH,NH2 (1 or 2 equiv). 37 LDA, -78 °C (-H20) Grignard, Wittig and Gilman Reagents: Assume "then H,0" is included if a protonation step is needed MgBr MeMgBr EtMgBr PhMgBr G1 G2 G3 G4 CuLi Me,Culi Et,Culi (PHCH2),CULI 38 NaH, 25 °C 39 LIAI(OR);H, then H20 40 DIBAH, then H2O 41 Br2. [H3O*] 42 Br2, NaOH 43 Pyridine G5 G6 G7 G8 MePh,P=CH2 PhyP=CHCH3 PhyP=CHCO,Et PhyP=CHPH W1 w2 W3 W4
Using the reagent list, identify the two components needed to make the compound below via an Aldol reaction. enolate in the reaction. Enolate component Other component
Transcribed Image Text:Using the reagent list, identify the two components needed to make the compound below via an Aldol reaction. enolate in the reaction. Enolate component Other component
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