Draw the curved arrow mechanism for the first step toward the major product in the nitration of 2,6-dibromopyridine with NO2+ (step 1) generated from HNO3 and H2SO4. If you predicted the correct regiochemistry in the first step, then the nitrogen in the ring should not be postively charged in any major resonance contributors of the intermediate. From the step 1 product, draw a single curved arrow leading to the step 2 resonance contributor. Draw all curved arrows, atoms, electrons, and charges, if necessary, on all structures; do not draw any inorganic side products or counterions. The structures should all have a neutral nitrogen in the ring.
Draw the curved arrow mechanism for the first step toward the major product in the nitration of 2,6-dibromopyridine with NO2+ (step 1) generated from HNO3 and H2SO4. If you predicted the correct regiochemistry in the first step, then the nitrogen in the ring should not be postively charged in any major resonance contributors of the intermediate. From the step 1 product, draw a single curved arrow leading to the step 2 resonance contributor. Draw all curved arrows, atoms, electrons, and charges, if necessary, on all structures; do not draw any inorganic side products or counterions. The structures should all have a neutral nitrogen in the ring.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the curved arrow mechanism for the first step toward the major product in the nitration of 2,6-dibromopyridine with NO2+ (step 1) generated from HNO3 and H2SO4. If you predicted the correct regiochemistry in the first step, then the nitrogen in the ring should not be postively charged in any major resonance contributors of the intermediate. From the step 1 product, draw a single curved arrow leading to the step 2 resonance contributor. Draw all curved arrows, atoms, electrons, and charges, if necessary, on all structures; do not draw any inorganic side products or counterions. The structures should all have a neutral nitrogen in the ring.
Transcribed Image Text:Step 1
H.
H
H
-N
Br
=Ö.
Step 2
H.
H
=0,
Br
-Ö:
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