(D) Draw the phosphoylide you would use to accomplish the H—> I transformation and why is the double bond in the E configuration? (E) There is a hemiacetal-aldehyde equilibrium between M and N. Draw just the northern half of N of the aldehyde form. (F) Draw the phosphoylide you would use to accomplish the N—> O transformation and predict the stereochemistry about the C=C double bond in O; is it E or Z?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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(D) Draw the phosphoylide you would use to accomplish the H—> I transformation and why is the double bond in the E configuration? (E) There is a hemiacetal-aldehyde equilibrium between M and N. Draw just the northern half of N of the aldehyde form. (F) Draw the phosphoylide you would use to accomplish the N—> O transformation and predict the stereochemistry about the C=C double bond in O; is it E or Z?
H3C
K
НО
L
0
F
-OCH3
OH
C5H11
C5H11
О
H3C
H3C
0
G
ОН
\\CH2CH=CH(CH2)3CO2
.C5H11
OH
ОН
M
H3C
С H11 H3C
C5H11
P
N
Н
Н
-C5H11
C5H11
CH₂CH=CH(CH2)3CO2
Pro
PG|
Pac
125
Transcribed Image Text:H3C K НО L 0 F -OCH3 OH C5H11 C5H11 О H3C H3C 0 G ОН \\CH2CH=CH(CH2)3CO2 .C5H11 OH ОН M H3C С H11 H3C C5H11 P N Н Н -C5H11 C5H11 CH₂CH=CH(CH2)3CO2 Pro PG| Pac 125
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