Draw a structural formula for the major organic product of the reaction shown below. CH3(CH2)5CH2 CuLi

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Chapter1: Chemical Foundations
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**Reaction Description:**

The image presents a chemical reaction where you are asked to draw the structural formula for the major organic product. It involves the following reactants:

1. **Reactant 1:** An alkyl iodide, specifically 1-iodo-1-octene, with the formula CH₃(CH₂)₅CH=CHI.
   
2. **Reactant 2:** A Gilman reagent, specifically lithium di-n-butylcuprate, with the formula (C₄H₉)₂CuLi. The reagent is shown in parentheses and has two n-butyl groups (C₄H₉).

**Explanation of Reaction:**

- **Gilman Reagent Reaction:** This is a typical coupling reaction using a Gilman reagent. These reagents are effective for forming carbon-carbon bonds by facilitating the replacement of the iodide group in the organic iodide with an organocopper species.

**Expected Product:**

- The iodine atom in the alkyl iodide is replaced by the butyl group from the Gilman reagent.
- The expected major product is butyl-1-octene.

In summary, the reaction involves replacing the iodine group in the alkyl iodide with one of the butyl groups from the Gilman reagent, resulting in the formation of butyl-1-octene as the major product.
Transcribed Image Text:**Reaction Description:** The image presents a chemical reaction where you are asked to draw the structural formula for the major organic product. It involves the following reactants: 1. **Reactant 1:** An alkyl iodide, specifically 1-iodo-1-octene, with the formula CH₃(CH₂)₅CH=CHI. 2. **Reactant 2:** A Gilman reagent, specifically lithium di-n-butylcuprate, with the formula (C₄H₉)₂CuLi. The reagent is shown in parentheses and has two n-butyl groups (C₄H₉). **Explanation of Reaction:** - **Gilman Reagent Reaction:** This is a typical coupling reaction using a Gilman reagent. These reagents are effective for forming carbon-carbon bonds by facilitating the replacement of the iodide group in the organic iodide with an organocopper species. **Expected Product:** - The iodine atom in the alkyl iodide is replaced by the butyl group from the Gilman reagent. - The expected major product is butyl-1-octene. In summary, the reaction involves replacing the iodine group in the alkyl iodide with one of the butyl groups from the Gilman reagent, resulting in the formation of butyl-1-octene as the major product.
Expert Solution
Step 1: Interpretation of given problem

Given reaction is addition of Gilman reagent on alkenyl halide.

Gilman reagent is represented as R2CuLi (Lithium dialkylcuprate).  Gilman reagent is the source of nucleophile and it undergoes 1,4- addition conjugated system and displaces the halogens by SN2 way.  

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