Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Reaction Mechanism Assignment**
**Task:** Draw a stepwise mechanism using arrows to show electron movement and draw each intermediate formed for the following reaction.
**Reactants and Reagents:**
- Starting Compound: Unsaturated alcohol with the structure containing a double bond and an -OH group.
- Reagent: Acidic Conditions (H₃O⁺)
**Product:**
- Cyclized ether with a five-membered ring.
**Instructions:**
1. **Identify Starting Material:**
- The starting alcohol has a double bond adjacent to a hydroxyl group, indicating potential for intramolecular reaction under acidic conditions.
2. **Apply Acidic Conditions:**
- Protonation of the hydroxyl group to facilitate water leaving, forming a carbocation.
3. **Carbocation Stability:**
- Consider possible rearrangements for carbocation stability.
4. **Cyclization:**
- Intramolecular nucleophilic attack by the double bond on the carbocation leads to ring closure, forming a five-membered ether ring.
5. **Final Product Confirmation:**
- Ensure the newly formed ether matches the structure shown.
Utilize electron-pushing arrows to clearly depict each step of the mechanism. Consider resonance and intermediate stability throughout the process.
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