Determine the rate of formation of HBr considering the mechanism of chain reaction, i.e.: (a) Initiation: Br2 - 2Br (b) Propagation of the chain: k2/k2 Br +H2 HBr + H' (radical) k3 Н + Brz (cycle of 106 times) HBr|+ Br* (c) Termination: 2Br- k4 Br2

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Determine the rate of formation of HBr considering the mechanism of chain reaction, i.e.:
(a) Initiation:
Br2
k1
2Br
(b) Propagation of the chain:
k2/k2
Br + H2
HBr + H' (radical)
k3
Н + Brz
(cycle of 106 times)
HBr| + Br
(c) Termination:
2Br
k4
Br2
Transcribed Image Text:Determine the rate of formation of HBr considering the mechanism of chain reaction, i.e.: (a) Initiation: Br2 k1 2Br (b) Propagation of the chain: k2/k2 Br + H2 HBr + H' (radical) k3 Н + Brz (cycle of 106 times) HBr| + Br (c) Termination: 2Br k4 Br2
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