Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![**Educational Content: Molecule Hybridization and Bond Angles**
In the displayed molecule, identify the hybridization and approximate bond angle of the labeled atoms:
- **a (Oxygen atom)**: Typically, oxygen in this context will exhibit sp³ hybridization, characterized by a bond angle close to 109.5°, due to its two lone pairs.
- **b (Carbon atom connected to oxygen and sulfur)**: Demonstrates sp³ hybridization, with a geometrical bond angle around 109.5°, owing to its tetrahedral arrangement.
- **c (Carbon atom double-bonded to another carbon)**: This carbon will be sp² hybridized, typical of alkenes, with an approximate bond angle of 120° due to its planar trigonal configuration.
- **d (Carbon atom with a lone pair)**: The presence of the lone pair indicates sp hybridization, associated with a linear geometry and a bond angle of approximately 180°.
- **e (Phosphorus atom connected to sulfur)**: This phosphorus is likely sp³ hybridized, suggesting a bond angle of about 109.5°, consistent with its tetrahedral shape.
- **f (Sulfur atom connected to phosphorus)**: With a similar sp³ hybridization, the sulfur exhibits a bond angle near 109.5°, being part of a different tetrahedral structure.
These hybridizations and bond angles are fundamental in predicting molecular geometry and behavior in various chemical environments.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdc1721bb-87af-4432-b926-b704463d725f%2F13520c74-1245-4a72-9b8c-6fa8bf616cb3%2F9nubrdq_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Educational Content: Molecule Hybridization and Bond Angles**
In the displayed molecule, identify the hybridization and approximate bond angle of the labeled atoms:
- **a (Oxygen atom)**: Typically, oxygen in this context will exhibit sp³ hybridization, characterized by a bond angle close to 109.5°, due to its two lone pairs.
- **b (Carbon atom connected to oxygen and sulfur)**: Demonstrates sp³ hybridization, with a geometrical bond angle around 109.5°, owing to its tetrahedral arrangement.
- **c (Carbon atom double-bonded to another carbon)**: This carbon will be sp² hybridized, typical of alkenes, with an approximate bond angle of 120° due to its planar trigonal configuration.
- **d (Carbon atom with a lone pair)**: The presence of the lone pair indicates sp hybridization, associated with a linear geometry and a bond angle of approximately 180°.
- **e (Phosphorus atom connected to sulfur)**: This phosphorus is likely sp³ hybridized, suggesting a bond angle of about 109.5°, consistent with its tetrahedral shape.
- **f (Sulfur atom connected to phosphorus)**: With a similar sp³ hybridization, the sulfur exhibits a bond angle near 109.5°, being part of a different tetrahedral structure.
These hybridizations and bond angles are fundamental in predicting molecular geometry and behavior in various chemical environments.
Expert Solution
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Step 1
Hybridization = Bond pair + Lone pair
By using this formula , we can calculate the hybridization of each atom.
For 2 , hybridization is 'sp' , Bond angle is 180
For 3 , hybridization is 'sp2' , Bond angle is 120
For 4, hybridization is 'sp3', Bond angle is 109.5
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