Determine the free energy change when silver chloride form at 25℃ Ag+ (aq) + Cl– (aq) → AgCl (s) Delta G = ?
Determine the free energy change when silver chloride form at 25℃ Ag+ (aq) + Cl– (aq) → AgCl (s) Delta G = ?
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
Determine the free energy change when silver chloride form at 25℃
Ag+ (aq) + Cl– (aq) → AgCl (s)
Delta G = ?
Transcribed Image Text:APPENDIX B
Standard Thermodynamic Values
for Selected Substances*
S°
(J/mol-K)
AH;
(kJ/mol)
AG;
(kJ/mol)
Substance
S°
AG;
(kJ/mol)
Substance
AH;
or lon
(kJ/mol)
or lon
(J/mol-K)
38.2
CaO(s)
Са(ОН), (s)
Ca3(PO4)2(s)
CASO4(s)
-635.1
-603.5
e (g)
Aluminum
20.87
-986.09
-898.56
83.39
28.3
-4138
-3899
263
Al(s)
Al*(aq)
-524.7
-481.2
-313
-1432.7
-1320.3
107
-704.2
-628.9
110.7
Carbon
AICI3(s)
Al,03(s)
50.94
5.686
C(graphite)
C(diamond)
C(g)
CO(g)
CO2(g)
CO2(aq)
CO (aq)
HCO;(aq)
H,CO;(aq)
CH4(g)
C,H¿(g)
C„H4(g)
CH6(g)
C;Hs(g)
C,H10(8)
C,H6(1)
CH;OH(g)
CH;OH(I)
НСНО(g)
HCOO¯(aq)
НСООН()
НСООН(аq)
CH;OH(g)
CH;OH(I)
CH;CHO(g)
CH;COOH(I)
C,H12O6(s)
C12H2„O|(s)
CN (aq)
HCN(g)
HCN(1)
HCN(aq)
CS-(g)
CS (1)
CH;CI(g)
CH,Cl2(1)
CHCI3(1)
CCL4(g)
-1676
-1582
Barium
1.896
2.866
2.439
62.5
715.0
669.6
158.0
Ba(s)
Ba(g)
Ba*(g)
Ba"(aq)
ВаCl(s)
BaCO3(s)
BaO(s)
BaSO,(s)
175.6
144.8
170.28
-110.5
-137.2
197.5
1649.9
-393.5
-394.4
213.7
-386.2
-528.10
-538.36
-560.7
13
-412.9
121
-806.06
-810.9
126
-676.26
-53.1
-1219
-1139
112
-691.11
587.06
95.0
-548.1
-520.4
72.07
-698.7
-623.42
191
-74.87
227
-1465
-1353
132
-50.81
186.1
Boron
209
200.85
52.47
68.36
219.22
B(B-rhombo-
hedral)
BF;(g)
BCl;(g)
B,H6(g)
B,03(s)
H;BO3(s)
Bromine
5.87
-84.667
-32.89
229.5
-1137.0
-1120.3
254.0
-105
-24.5
269.9
-403.8
-388.7
290.0
-126
-16.7
310
35
86.6
232.0
49.0
124.5
172.8
-1272
-1193
53.8
-201.2
-161.9
238
-1094.3
-969.01
88.83
-238.6
-166.2
127
-116
-110
219
152.23
-410
-335
91.6
Br2(1)
Br2(g)
Br(g)
Br (g)
Br (aq)
HBr(g)
Cadmium
-346
-356
30.91
3.13
245.38
-409
129.0
111.9
82.4
174.90
-410
164
-218.9
-235.1
-168.6
282.6
-120.9
-102.82
80.71
-277.63
-174.8
161
-36.3
-53.5
198.59
-166
-133.7
266
-487.0
-392
160
51.5
-1273.3
-910.56
212.1
Cd(s)
Cd(g)
Cd*(aq)
CdS(s)
112.8
78.2
167.64
-2221.7
-1544.3
360.24
118
201.7
-72.38
-77.74
-61.1
151
166
-144
-141
71
135
125
Calcium
105
121.
112.8
Ca(s)
41.6
105
112
129
66.9
63.6
192.6
158.9
154.78
117
237.79
Ca(g)
Ca*(g)
Ca*(aq)
CaF2(s)
CaCl2(s)
CACO3(s)
1934.1
87.9
151.0
-542.96
-553.04
-55.2
-83.7
-60.2
234
-1215
-1162
68.87
-117
-63.2
179
-795.0
-750.2
114
-132
-71.5
203
-1206.9
-1128.8
92.9
-96.0
-53.7
309.7
*All values at 298 K.
(сontinued)
A-5
Transcribed Image Text:A-6
Appendix B • Standard Thermodynamic Values for Selected Substances
Appendix B. Standard Thermodynamic Values for Selected Substances
А-7
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
or lon
(J/mol-K)
or lon
(J/mol-K)
or lon
(J/mol-K)
or lon
(J/mol-K)
CCl,(1)
COCI2(8)
Cesium
Cs(s)
Cs(g)
Cs*(g)
Cs*(aq)
CsF(s)
CSCI(s)
CsBr(s)
CsI(s)
-68.6
-206
-139
214.4
FeCl3(s)
FeO(s)
Fe,03(s)
Fe;O4(s)
-399.5
AgF(s)
AgCl(s)
AgBr(s)
AgI(s)
AGNO3(s)
Ag,S(s)
Sodium
-334.1
142
155.6
-203
-185
84
HNO3(1)
HNO3(aq)
NF3(g)
NOCI(g)
NH,CI(s)
Охудen
O2(g)
O(g)
03(8)
ОН (ад)
H,O(g)
H2O(1)
H,O2(1)
H,O,(aq)
Phosphorus
P4(s, white)
P(g)
P(s, red)
P2(8)
PĄ(8)
PCI3(8)
PCI3(1)
PCI5(g)
PCI3(s)
P,O10(s)
PO (aq)
НРО (ад)
H,PO, (aq)
H;PO4(aq)
H;PO,(1)
Potassium
-173.23
-79.914
-220
283.74
-272.0
-251.4
-206.57
-110.5
146
-127.03
-109.72
96.11
60.75
87.400
145.3
-825.5
-743.6
-95.939
-66.32
-125
-83.3
260.6
-99.51
107.1
85.15
-1121
-1018
51.71
66.07
261.6
-62.38
114
76.7
49.7
175.5
Lead
94.6
-45.06
19.1
-40.3
-314.4
-203.0
128.2
458.5
427.1
169.72
Pb(s)
Pb*(aq)
PbCl2(s)
PbO(s)
PbO2(s)
PbS(s)
PbSO,(s)
-31.8
146
64.785
21
-248
-282.0
133
1.6
-24.3
205.0
-554.7
-525.4
88
-359
-314
249.2
231.7
160.95
Na(s)
Na(g)
Na*(g)
Na*(aq)
NaF(s)
NaCl(s)
NaBr(s)
NaOH(s)
Na,CO3(s)
NaHCO3(s)
NaI(s)
Strontium
136
51.446
-442.8
-395
-414
101.18
-218
-198
68.70
143
163
238.82
107.76
77.299
153.61
-383
121
-276.6
-219.0
-157.30
-228.60
76.6
-229.94
-10.54
609.839
574.877
147.85
-337
-333
130
-98.3
-96.7
91.3
-241.826
188.72
-239.66
-261.87
60.2
Chlorine
-918.39
-811.24
147
-285.840
-237.192
69.940
-575.4
-545.1
51.21
Cl2(g)
Cl(g)
CI"(g)
CI"(aq)
HCI(g)
HCI(aq)
CIO2(g)
Cl,0(g)
Chromium
223.0
Lithium
-187.8
-120.4
110
-411.1
-384.0
72.12
121.0
105.0
165.1
Li(s)
Li(g)
Li*(8)
Li*(aq)
LiF(s)
LİCI(s)
LiBr(s)
LiI(s)
Magnesium
Mg(s)
Mg(g)
Mg**(g)
Mg**(aq)
MgCl2(s)
MGCO3(s)
MgO(s)
Mg;N2(s)
Manganese
Mn(s, c)
Mn*(aq)
MnOg(s)
MnO, (aq)
Mercury
Hg(1)
Hg(g)
Hg²*(aq)
Hg*(aq)
HgCl½(s)
Hg,Cl,(s)
HgO(s)
Nitrogen
N2(g)
N(g)
N20(g)
NO(g)
NO2(g)
N,O3(g)
N204(8)
N2O5(g)
N,O5(s)
NH3(g)
NH3(aq)
N2H4(1)
NO (aq)
144
-349
86.82
29.10
138.67
132.91
-191.2
-134.1
-361
-234
-240
153.25
161
128
-425.609
-379.53
64.454
-167.46
-131.17
55.10
687.163
649.989
41.1
-1130.8
-1048.1
139
-92.31
-95.30
186.79
-278.46
-293.8
14
314.6
278.3
163.1
-947.7
-851.9
102
-167.46
-131.17
55.06
-616.9
-588.7
-384
35.66
-17.6
-12.1
22.8
-288
-285
98.5
102
120
256.7
-408
59.30
144
104
218
80.3
97.9
266.1
-351
-342
Sr(s)
Sr(g)
Sr*(g)
Sr*(aq)
SrCl2(s)
SrCO3(s)
SrO(s)
SrSO,(s)
Sulfur
74.1
58.9
24.5
280
54.4
-270
-270
85.8
-287
-268
312
164
110
164.54
Cr(s)
Cr**(aq)
Cro (aq)
Cr,O (aq)
Сopper
Cu(s)
Cu(g)
Cu*(aq)
Cu²*(aq)
Cu,O(s)
CuO(s)
Cu,S(s)
CuS(s)
Fluorine
23.8
-320
-272
217
1784
-1971
32.69
-402
-443.5
-2984
-323
353
-545.51
-557.3
-39
-863.2
-706.3
38
150
115
148.55
-828.4
-781.2
117
-1461
-1257
214
2351
-2698
229
-1218
-1138
97.1
-461.96
-456.01
118
-1266
-1013
-218
-592.0
-562.4
55.5
33.1
-641.6
-592.1
89.630
-1281
-1082
-36
-1445
-1334
122
341.1
301.4
166.29
-1112
-1028
65.86
26.9
-1285
-1135
89.1
51.9
64.39
50.2
-26
S(rhombic)
S(monoclinic)
S(g)
S2(g)
S8(g)
s (aq)
HS¯(aq)
H,S(g)
H,S(aq)
SO2(g)
SO:(8)
SO (aq)
HSO,(aq)
H;SO,(1)
H,SO4(aq)
-601.2
-461
-569.0
-1277
-1019
228
31.9
64.98
-98.7
-401
88
-1271.7
-1123.6
150.8
0.3
0.096
32.6
-168.6
-146.0
93.1
279
239
168
-157.3
-130
42.63
31.8
64.672
129
80.1
228.1
K(s)
K(g)
K*(g)
K*(aq)
KF(s)
KCI(s)
KBr(s)
KI(s)
КОН(:)
KCIO;(s)
KCIO:(s)
-79.5
-86.2
120.9
-219
-223
-84
89.2
60.7
160.23
101
49.1
430.211
-53.1
-53.6
66.5
-520.9
-466.1
53.1
514.197
481.202
154.47
41.8
83.7
22
-518.4
-425.1
190
-251.2
-282.28
103
-17.7
12.6
61.1
F2(g)
F(g)
F (g)
F (aq)
HF(g)
Hydrogen
H2(g)
H(g)
H*(aq)
H*(g)
202.7
-568.6
-538.9
66.55
-20.2
-33
205.6
78.9
61.8
158.64
76.027
-436.7
-409.2
82.59
-39
-27.4
122
-255.6
-262.5
145.47
61.30
31.8
174.87
-394
-380
95.94
-296.8
-300.2
248.1
-329.1
-276.5
-9.6
171
164.4
-32
-328
-323
106.39
-396
-371
256.66
-273
-275
173.67
172
153.6
84.5
-424.8
-379.1
78.87
-907.51
-741.99
17
-230
-264.9
-885.75
-813.989
-184
144
-397.7
-296.3
143.1
-752.87
126.9
0.
130.6
-210.66
196
-432.75
-303.2
151.0
-690.059
156.90
218.0
203.30
114.60
-90.79
-58.50
70.27
Rubidium
-907.51
-741.99
17
Rb(s)
Rb(g)
Rb*(g)
Rb*(aq)
RbF(s)
RbCl(s)
RbBr(s)
RbI(s)
Silicon
69.5
Tin
1536.3
1517.1
108.83
191.5
153.2
Sn(white)
Sn(gray)
SnCl,(1)
SnO2(s)
Titanium
85.81
55.86
169.99
51.5
Iodine
473
456
495.04
3
4.6
44.8
L(s)
L(8)
I(g)
I(g)
I(aq)
HI(g)
-116.14
82.05
104.2
219.7
-246
-282.2
124
-545.2
-474.0
259
62.442
19.38
70.21
260.58
90.29
86.60
210.65
-549.28
-580.7
-519.7
52.3
106.8
180.67
33.2
51
239.9
-435.35
-407.8
95.90
-194.7
86.6
142.4
314.7
108.3
Ti(s)
TiCl,(1)
TiO2(s)
-389.2
-378.1
30.7
-55.94
-51.67
109.4
304.3
346
9.16
97.7
-328
-326
118.0
-804.2
-737.2
252.3
25.9
1.3
206.33
11
118
-944.0
-888.8
50.6
Iron
-43.1
114
178
Zinc
Si(s)
SiF,(g)
SiO2(s)
0.
18.0
Fe(s)
Fe*(aq)
Fe*(aq)
FeCl2(s)
27.3
193
110
-45.9
-16
-1614.9
-1572.7
282.4
Zn(s)
41.6
-47.7
-10.5
-293
-80.83
26.7
160.9
Zn(g)
Zn²*(aq)
ZnO(s)
ZnS(s, zinc
blende)
-910.9
-856.5
41.5
130.5
94.93
-87.9
-84.94
113
50.63
149.2
121.2
Silver
-152.4
-147.21
-106.5
-341.8
-302.3
117.9
-206.57
-110.5
146
42.702
-348.0
-318.2
43.9
Ag(s)
Ag(g)
Ag*(aq)
289.2
250.4
172.892
-203
-198
57.7
(continued)
105.9
77.111
73.93
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemical-engineering and related others by exploring similar questions and additional content below.Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The